(±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

Base Information

Chemical Name:(±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone
CAS No.:1187055-95-3
Molecular Formula:C12H12N2O3
Molecular Weight:232.239
Hs Code.:
Mol file:1187055-95-3.mol

Synonyms:2-CYCLOHEXEN-1-ONE, 5-METHYL-3-(3-NITRO-4-PYRIDINYL)-;5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone;5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-en-1-one;

Suppliers and Price of (±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
5-Methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone
2.5mg
$ 45.00

Matrix Scientific
5-Methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone 95%
2.500g
$ 2146.00

Crysdot
5-Methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone 95+%
1g
$ 1188.00

Chemenu
5-Methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone 95%
1g
$ 1119.00

AK Scientific
5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-en-1-one
100mg
$ 438.80

AK Scientific
5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-en-1-one
1g
$ 1346.00

A1 Biochem Labs
5-Methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone 95%
2.5 g
$ 1300.00

Total 4 raw suppliers

Chemical Property of (±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

Chemical Property:

PSA：75.78000
LogP:2.89540

Purity/Quality:

99% ^*data from raw suppliers

5-Methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

There total 3 articles about (±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 1187055-94-2
5-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohex-2-en-1-one

: 13091-23-1
4-chloro-3-nitropyridine

: 1187055-95-3
(±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; sodium carbonate; In 1,4-dioxane; water; for 1h; Inert atmosphere; Reflux;

Reference yield:

: 1187055-93-1
5-methyl-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate

: 1187055-95-3
(±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: potassium acetate / dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂ / 1,4-dioxane / 10 h / 80 °C

2: sodium carbonate / dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂ / 1,4-dioxane / 1 h / 110 °C

With potassium acetate; sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In 1,4-dioxane;

Reference yield:

: 4341-24-6
5-methylcyclohexan-1,3-dione

: 1187055-95-3
(±)-5-methyl-3-(3-nitropyridin-4-yl)cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: sodium carbonate / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

2: potassium acetate / dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂ / 1,4-dioxane / 10 h / 80 °C

3: sodium carbonate / dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂ / 1,4-dioxane / 1 h / 110 °C

With potassium acetate; sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In 1,4-dioxane; dichloromethane;