1- (three f) -1- hydroxy -5- - O - ring of 3- ketone

Base Information

Chemical Name:1- (three f) -1- hydroxy -5- - O - ring of 3- ketone
CAS No.:1187055-93-1
Molecular Formula:C8H9F3O4S
Molecular Weight:258.218
Hs Code.:
Mol file:1187055-93-1.mol

Synonyms:1- (three f) -1- hydroxy -5- - O - ring of 3- ketone;5-methyl-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate

Suppliers and Price of 1- (three f) -1- hydroxy -5- - O - ring of 3- ketone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of 1- (three f) -1- hydroxy -5- - O - ring of 3- ketone

Chemical Property:

PSA：68.82000
LogP:2.81630

Purity/Quality:: 99.0.% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of 1- (three f) -1- hydroxy -5- - O - ring of 3- ketone

There total 2 articles about 1- (three f) -1- hydroxy -5- - O - ring of 3- ketone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 4341-24-6
5-methylcyclohexan-1,3-dione

: 358-23-6
trifluoromethylsulfonic anhydride

: 1187055-93-1
5-methyl-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: With sodium carbonate; In dichloromethane; at 0 - 20 ℃; for 2h; Inert atmosphere;

Reference yield:

: 4341-24-6
5-methylcyclohexan-1,3-dione

: 1187055-93-1
5-methyl-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: With Tf₂O; sodium hydrogencarbonate; sodium carbonate; In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran;

Reference yield:

: 1187055-93-1
5-methyl-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate

: 73183-34-3
bis(pinacol)diborane

: 1187055-94-2
5-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohex-2-en-1-one

Guidance literature:: With potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In 1,4-dioxane; at 80 ℃; for 10h;