1,3,2,4-Dioxadithiane, 2,2,4,4-tetraoxide

Base Information

• Chemical Name: 1,3,2,4-Dioxadithiane, 2,2,4,4-tetraoxide
• CAS No.: 503-41-3
• Molecular Formula: C2H4 O6 S2
• Molecular Weight: 188.182
• Hs Code.: 2934999090
• European Community (EC) Number: 207-968-5
• UNII: HSJ374FH79
• DSSTox Substance ID: DTXSID8060119
• Nikkaji Number: J61.295B
• Wikipedia: Carbyl_sulfate
• Wikidata: Q1035566
• Mol file: 503-41-3.mol

Synonyms:1,3,2,4-dioxadithiane 2,2,4,4-tetraoxide;503-41-3;1,3,2,4-Dioxadithiane, 2,2,4,4-tetraoxide;carbyl sulfate;1,3,2,4-Dioxadithiane, 2,2,4,4-tetroxide;HSJ374FH79;EINECS 207-968-5;Carbyl sulphate;UNII-HSJ374FH79;SCHEMBL4070806;DTXSID8060119;C2-H4-O6-S2;AKOS026749740;FT-0699775;1,3,2|E?,4|E?-dioxadithiane-2,2,4,4-tetrone;Q1035566;Ethanesulfonic acid, 2-hydroxy-, hydrogen sulfate, cyclic anhydride

Chemical Property of 1,3,2,4-Dioxadithiane, 2,2,4,4-tetraoxide

Chemical Property:

• Vapor Pressure: 0.000383mmHg at 25°C
• Melting Point: 80°C
• Refractive Index: 1.5300 (estimate)
• Boiling Point: 327.5°C at 760 mmHg
• Flash Point: 151.9°C
• PSA: 103.50000
• Density: 1.85g/cm³
• LogP: 0.76940
• XLogP3: -1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 187.94493019
• Heavy Atom Count: 10
• Complexity: 297

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CS(=O)(=O)OS(=O)(=O)O1
• Use Description: 1,3,2,4-dioxadithiane 2,2,4,4-tetraoxide, also known as peroxyacetaldehyde dioxetane, has applications in various fields. In the field of chemistry and analytical chemistry, it serves as a chemiluminescent reagent for detecting the presence of peroxides and reactive oxygen species. Its role is fundamental in chemical assays and detection methods, providing a sensitive and selective means of measuring oxidative stress and peroxide concentrations in various samples. Moreover, in the field of biotechnology and molecular biology, it is employed as a chemiluminescent substrate for various enzyme-linked immunosorbent assays (ELISAs) and detection of biomolecules such as antibodies and proteins. Its significance varies within these fields, but it consistently plays a pivotal role in advancing chemical analysis, molecular biology, and diagnostic techniques across diverse scientific and industrial applications.

Technology Process of 1,3,2,4-Dioxadithiane, 2,2,4,4-tetraoxide

There total 5 articles about 1,3,2,4-Dioxadithiane, 2,2,4,4-tetraoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

ethanol (64-17-5) → 2-sulfooxy-ethanesulfonic acid (461-42-7) + carbyl sulfate (503-41-3)

Guidance literature:

With sulfur trioxide; at 75 - 80 ℃; Temperature; Flow reactor;

Reference yield:

ethene (74-85-1) → carbyl sulfate (503-41-3)

Guidance literature:

With sulfur trioxide;

Reference yield:

2-hydroxyethanesulfonic acid (107-36-8) → carbyl sulfate (503-41-3)

Guidance literature:

With sulfur trioxide;

upstream raw materials:

ethanol

ethene

2-hydroxyethanesulfonic acid

Downstream raw materials:

N-(p-tolyl)ethenesulfonamide

ethenesulfonic acid p-phenetidide

2-chlorophenyl ethenesulfonate

2-chloroethanesulphonic acid

Refernces

Rhodium carbenoid induced cycloadditions of diazo ketoimides across indolyl π-bonds

10.1055/s-2007-967982

The research focuses on the rhodium carbenoid induced cycloadditions of diazo ketoimides across indolyl p-bonds. The experiments involve the preparation of a series of diazo ketoimides from (1H-indol-3yl)acetyl chloride and alkyl 2-diazo-3-(3-substituted-2-oxopiperidin-3-yl)-3-oxopropanoates, which are then treated with rhodium(II) acetate. The key reaction is the attack of the imido carbonyl oxygen at the rhodium carbenoid center, leading to the formation of a transient push–pull carbonyl ylide dipole. This dipole undergoes an intramolecular dipolar cycloaddition across the indole p-bond, resulting in the formation of cycloadducts. The study explores the influence of substituents on the dipole's approach to the indole ring, with a focus on endo- and exo-cycloaddition products. The experiments utilize techniques such as X-ray crystal structure analysis for stereochemical assignments and involve the use of reagents like Lawesson's reagent and Raney-Ni for reduction steps. The analyses include infrared spectroscopy (IR) and nuclear magnetic resonance (NMR) to characterize the synthesized compounds.

Reactions of macrocyclic rhodium carbenoids: regioselective synthesis of indol-3-yl macrocyclic lactones and cryptands

10.1016/j.tetlet.2007.11.102

The research focuses on the synthesis and reactions of macrocyclic rhodium carbenoids, specifically targeting the regioselective synthesis of indol-3-yl macrocyclic lactones and cryptands. The experiments involved the preparation of a variety of macrocyclic diazocarbonyl compounds with different spacers, which were then reacted with rhodium(II) carbenoids generated from α-diazocarbonyl compounds and rhodium(II) carboxylates. This approach led to the formation of C–C bonds and the production of indol-3-yl macrocyclic di- or tetralactones through regioselective intermolecular alkylation/insertion. The study also explored double carbenoid insertion to synthesize indolyl cryptand molecules. The reactants included macrocyclic diazocarbonyl compounds, various substituted indoles, and rhodium(II) acetate as a catalyst. Analytical techniques such as nuclear magnetic resonance (NMR) spectroscopy and high-resolution mass spectrometry (HRMS) were employed to characterize the synthesized compounds, confirming the structure and purity of the products.

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