N-Benzoyl-S-phenyl-S-methylsulfoximine

Base Information

• Chemical Name: N-Benzoyl-S-phenyl-S-methylsulfoximine
• CAS No.: 54090-90-3
• Molecular Formula: C14H13NO2S
• Molecular Weight: 259.329
• Mol file: 54090-90-3.mol

Synonyms:N-Benzoyl-S-methyl-S-phenylsulfoximide;N-Benzoyl-S-phenyl-S-methylsulfoximine

Chemical Property of N-Benzoyl-S-phenyl-S-methylsulfoximine

Chemical Property:

• Boiling Point: 410.9±28.0 °C(Predicted)
• PSA: 54.88000
• Density: 1.15±0.1 g/cm3(Predicted)
• LogP: 3.84940

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Benzoyl-S-phenyl-S-methylsulfoximine

There total 27 articles about N-Benzoyl-S-phenyl-S-methylsulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

racemic methyl phenyl sulfoxide (1193-82-4) + 3-phenyl-5H-1,4,2-dioxazol-5-one (19226-36-9) → N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (54090-90-3)

Guidance literature:

With carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II); In toluene; at 20 ℃; for 4h; Reagent/catalyst; Solvent; Time; Inert atmosphere; Irradiation;

DOI:10.1002/anie.201310790

Reference yield: 93.0%

benzoyl chloride (98-88-4) + S-methyl-S-phenylsulfoximine (4381-25-3) → N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (54090-90-3)

Guidance literature:

With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201200092

Reference yield: 93.0%

methyl-phenyl-thioether (100-68-5) + 3-phenyl-5H-1,4,2-dioxazol-5-one (19226-36-9) → N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (54090-90-3)

Guidance literature:

methyl-phenyl-thioether; 3-phenyl-5H-1,4,2-dioxazol-5-one; With carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II); In toluene; at 20 ℃; Irradiation; Inert atmosphere;

With sodium periodate; In dichloromethane; water; at 20 ℃;

DOI:10.1002/anie.201310790

upstream raw materials:

benzoyl chloride

S-methyl-S-phenylsulfoximine

methyl-phenyl-thioether

racemic methyl phenyl sulfoxide

Downstream raw materials:

C₁₈H₁₇NO₃S

C₁₈H₁₇NO₃S

N-[2,6-diacetoxybenzoyl]-S-methyl-S-phenylsulfoximine

N-[2-acetoxybenzoyl]-S-methyl-S-phenylsulfoximine