Bromozinc(1+);nonane

Base Information

• Chemical Name: Bromozinc(1+);nonane
• CAS No.: 626207-32-7
• Molecular Formula: C₉H₁₉BrZn
• Molecular Weight: 272.544
• DSSTox Substance ID: DTXSID00462028
• Mol file: 626207-32-7.mol

Synonyms:bromozinc(1+);nonane;626207-32-7;DTXSID00462028;MolPort-023-213-761

Chemical Property of Bromozinc(1+);nonane

Chemical Property:

• PSA: 0.00000
• LogP: 0.57260
• Sensitive.: Air Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 269.99615
• Heavy Atom Count: 11
• Complexity: 41.3

Purity/Quality:

98% ^*data from raw suppliers

n-Nonylzincbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCC[CH2-].[Zn+]Br

Technology Process of Bromozinc(1+);nonane

There total 1 articles about Bromozinc(1+);nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromononane (693-58-3) + zinc (7440-66-6) → n-nonylzinc bromide (626207-32-7)

Guidance literature:

zinc; With iodine; In N,N-dimethyl acetamide; at 20 ℃; for 0.166667h;

1-Bromononane; In N,N-dimethyl acetamide; at 80 ℃; for 3h;

DOI:10.1021/jm301304e

Reference yield: 70.0%

1-indene (95-13-6) + n-nonylzinc bromide (626207-32-7) → 1-nonylindane (29138-83-8)

Guidance literature:

With Pd(IiPr)(OTs)2; zinc trifluoromethanesulfonate; p-benzoquinone; In N,N-dimethyl acetamide; at 20 ℃; for 1.5h;

DOI:10.1021/ja908545b

upstream raw materials:

1-Bromononane

zinc

Downstream raw materials:

1-nonylindane

Refernces

• 1、 Liang, Yufan,Fu, Gregory C.. "Nickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent". supporting information. p. 9047 - 9051. Retrieved 2015/08/03.