2-Allyloxy-1,3,5-tribromobenzene

Base Information

• Chemical Name: 2-Allyloxy-1,3,5-tribromobenzene
• CAS No.: 3278-89-5
• Molecular Formula: C9H7Br3O
• Molecular Weight: 370.866
• Hs Code.: 2909309090
• European Community (EC) Number: 221-913-2
• NSC Number: 35767
• UNII: 2QB5393K07
• DSSTox Substance ID: DTXSID3044918
• Nikkaji Number: J71.655C
• Wikidata: Q27255479
• ChEMBL ID: CHEMBL3188631
• Mol file: 3278-89-5.mol

Synonyms:Benzene,1,3,5-tribromo-2-(2-propenyloxy)- (9CI);Ether, allyl 2,4,6-tribromophenyl(7CI,8CI);2,4,6-Tribromophenyl allyl ether;Allyl 2,4,6-tribromophenyl ether;NSC 35767;Pyroguard FR 100;

Chemical Property of 2-Allyloxy-1,3,5-tribromobenzene

Chemical Property:

• Vapor Pressure: 0.00018mmHg at 25°C
• Melting Point: 74-76 °C(lit.)
• Refractive Index: 1.599
• Boiling Point: 339.5 °C at 760 mmHg
• Flash Point: 138 °C
• PSA: 9.23000
• Density: 1.95 g/cm³
• LogP: 4.53890
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 369.80265
• Heavy Atom Count: 13
• Complexity: 162

Purity/Quality:

99% ^*data from raw suppliers

1,3,5-Tribromo-2-(2-propen-1-yloxy)-benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CCOC1=C(C=C(C=C1Br)Br)Br

Technology Process of 2-Allyloxy-1,3,5-tribromobenzene

There total 5 articles about 2-Allyloxy-1,3,5-tribromobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.2%

sodium 2,4,6-tribromophenolate (2666-53-7) + 3-chloroprop-1-ene (107-05-1) → 1,3,5-tribromo-2-prop-2-enoxybenzene (3278-89-5)

Guidance literature:

With sodium stearate; benzyltriethylammonium chloride; In ethanol; at 75 ℃; for 6.5h; Reagent/catalyst; Temperature;

Reference yield:

allyl bromide (106-95-6) + 2,4,6-tribromophenol (118-79-6) → 1,3,5-tribromo-2-prop-2-enoxybenzene (3278-89-5)

Guidance literature:

With potassium carbonate; acetone;

DOI:10.1021/ja01302a029

Reference yield:

3-chloroprop-1-ene (107-05-1) + 2,4,6-tribromophenol (118-79-6) → 1,3,5-tribromo-2-prop-2-enoxybenzene (3278-89-5)

Guidance literature:

With sodium hydroxide; ethanol;

DOI:10.1021/jo01166a015

upstream raw materials:

allyl bromide

2,4,6-tribromophenol

3-chloroprop-1-ene

allyl iodid

Downstream raw materials:

2,3-dibromopropyl 2,4,6-tribromophenyl ether

1,3,5-tribromo-2-propoxybenzene

2,4,6-Tribromophenyl (1-propenyl) ether

2-allyl-4,6-dibromophenol

Refernces

• 1、 Salunkhe, M.M.,Thorat, M.T.,Mane, R. B.,Sande, A.R.,Wadgaonkar, P.P.. "A SIMPLE AND EFFICIENT METHOD FOR PREPARATION OF ALLYL ARYL ETHERS VIA POLYMER SUPPORTED REAGENTS". . p. 691 - 694. Retrieved 2007/10/02.