Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Base Information

Chemical Name:Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate
CAS No.:1111096-29-7
Molecular Formula:C₁₂H₁₇BO₅
Molecular Weight:252.075
Hs Code.:2932190090
European Community (EC) Number:856-560-9
DSSTox Substance ID:DTXSID10682316
Wikidata:Q82606638
Mol file:1111096-29-7.mol

Synonyms:1111096-29-7;Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate;4-(METHOXYCARBONYL)FURAN-2-BORONIC ACID, PINACOL ESTER;4-(Methoxycarbonyl)furan-2-boronic acid pinacol ester;SCHEMBL2723584;DTXSID10682316;RAMMMHGDFUIABW-UHFFFAOYSA-N;methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3-furoate;MFCD12407248;AKOS015946137;AT16486;BS-23179;CS-0176355;FT-0700065;EN300-7387929;4-(Methoxycarbonyl)furan-2-boronic acid,pinacol ester;Z2050072549;METHYL 5-(TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FURAN-3-CARBOXYLATE;Methyl5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Suppliers and Price of Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-(Methoxycarbonyl)furan-2-boronicacid,pinacolester
250mg
$ 185.00

TRC
4-(Methoxycarbonyl)furan-2-boronicacid,pinacolester
1g
$ 415.00

Crysdot
Methyl5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate 95+%
5g
$ 706.00

Apolloscientific
4-(Methoxycarbonyl)furan-2-boronic acid, pinacol ester 98%
1g
$ 416.00

AK Scientific
4-(Methoxycarbonyl)furan-2-boronicacidpinacolester
5g
$ 1051.00

AK Scientific
4-(Methoxycarbonyl)furan-2-boronicacidpinacolester
1g
$ 384.00

Total 10 raw suppliers

Chemical Property of Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:252.1169038
Heavy Atom Count:18
Complexity:325

Purity/Quality:

98%min ^*data from raw suppliers

4-(Methoxycarbonyl)furan-2-boronicacid,pinacolester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC(=CO2)C(=O)OC

Technology Process of Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

There total 4 articles about Methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 13129-23-2
methyl furan-3-carboxylate

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1111096-29-7
methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Guidance literature:: 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; In tetrahydrofuran; at 22 ℃; for 0.5h; Inert atmosphere; Glovebox;

methyl furan-3-carboxylate; In tetrahydrofuran; at 22 ℃; Inert atmosphere; Glovebox;
DOI:10.1021/jacs.9b01567

Reference yield:

: 1073354-94-5
5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylic acid

: 18107-18-1
diazomethyl-trimethyl-silane

: 1111096-29-7
methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Guidance literature:: In methanol; for 0.75h;

Reference yield:

: 13129-23-2
methyl furan-3-carboxylate

: 73183-34-3
bis(pinacol)diborane

: 1111096-29-7
methyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-3-carboxylate

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; In tetrahydrofuran; at 80 ℃; for 24h; regioselective reaction; Inert atmosphere; Schlenk technique; Sealed tube;
DOI:10.1002/ejoc.201900583