(Z)-3-(Benzylthio)acrylic acid methyl ester

Base Information

Chemical Name:(Z)-3-(Benzylthio)acrylic acid methyl ester
CAS No.:77611-66-6
Molecular Formula:C11H12O2S
Molecular Weight:0
Hs Code.:
Mol file:77611-66-6.mol

Synonyms:(Z)-3-(Benzylthio)acrylic acid methyl ester;(Z)-3-[(Phenylmethyl)thio]propenoic acid methyl ester

Suppliers and Price of (Z)-3-(Benzylthio)acrylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (Z)-3-(Benzylthio)acrylic acid methyl ester

Chemical Property:

PSA：51.60000
LogP:2.60650

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (Z)-3-(Benzylthio)acrylic acid methyl ester

There total 5 articles about (Z)-3-(Benzylthio)acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 17830-98-7
(Z)-2-carbomethoxyethenyl thiolacetate

: 100-39-0
benzyl bromide

: 77611-66-6
(Z)-2-carbomethoxyethenyl benzyl thioether

Guidance literature:: (Z)-2-carbomethoxyethenyl thiolacetate; With caesium carbonate; In methanol; at -10 ℃;

benzyl bromide; In methanol; at -10 ℃; optical yield given as %de;
DOI:10.1002/ejoc.200801025

Reference yield:

: 922-67-8
propynoic acid methyl ester

: 100-53-8
phenylmethanethiol

: 77611-66-6
(Z)-2-carbomethoxyethenyl benzyl thioether

: 13831-00-0
trans-β-Benzylmercapto-acrylsaeure-methylester

Guidance literature:: With triethylamine; In acetonitrile; at 0 ℃;
DOI:10.1016/S0040-4039(03)01614-9

Reference yield:

: 607731-44-2
1-[[(Z)-2-(benzylsulfanyl)vinyl]sulfonyl]-4-methylbenzene

: 77611-66-6
(Z)-2-carbomethoxyethenyl benzyl thioether

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / pyrrolidine / acetonitrile / 20 °C

2: Et₃N / acetonitrile / 0 °C

With pyrrolidine; triethylamine; In acetonitrile;
DOI:10.1016/S0040-4039(03)01614-9