4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

Base Information

Chemical Name:4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane
CAS No.:1016641-70-5
Molecular Formula:C13H19BO3S
Molecular Weight:266.169
Hs Code.:2934999090
DSSTox Substance ID:DTXSID60682205
Mol file:1016641-70-5.mol

Synonyms:1016641-70-5;4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane;4-methylsulfinylphenylboronic acid, pinacol ester;4-Methylsulfinylphenylboronic acid pinacol ester;4,4,5,5-tetramethyl-2-(4-methylsulfinylphenyl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-[4-(methylsulfinyl)phenyl]-1,3,2-dioxaborolane;SCHEMBL3214269;DTXSID60682205;NWLRDFRSFJEVCD-UHFFFAOYSA-N;MFCD16660301;AKOS016004713;BS-19107;CS-0108348;FT-0724564;D76784;A926778;2-[4-(Methanesulfinyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)-phenyl)-1,3,2-dioxaborolane

Suppliers and Price of 4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-MethylsulfinylphenylboronicAcidPinacolEster
100mg
$ 90.00

TRC
4-MethylsulfinylphenylboronicAcidPinacolEster
50mg
$ 65.00

Matrix Scientific
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)-phenyl)-1,3,2-dioxaborolane 95+%
250mg
$ 265.00

Matrix Scientific
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)-phenyl)-1,3,2-dioxaborolane 95+%
1g
$ 588.00

Crysdot
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane 95+%
5g
$ 1310.00

Crysdot
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane 95+%
1g
$ 371.00

Chemenu
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane 95%
1g
$ 281.00

American Custom Chemicals Corporation
4,4,5,5-TETRAMETHYL-2-(4-(METHYLSULFINYL)PHENYL)-1,3,2-DIOXABOROLANE 95.00%
1G
$ 413.70

Alichem
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane
5g
$ 1320.00

Alichem
4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane
1g
$ 405.00

Total 10 raw suppliers

Chemical Property of 4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

Chemical Property:

PSA：54.74000
LogP:2.58890
Storage Temp.:Room temperature.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:266.1147958
Heavy Atom Count:18
Complexity:319

Purity/Quality:

97% ^*data from raw suppliers

4-MethylsulfinylphenylboronicAcidPinacolEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC=C(C=C2)S(=O)C

Technology Process of 4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

There total 3 articles about 4,4,5,5-Tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 190788-58-0
4,4,5,5-tetramethyl-2-(4-methylsulfanylphenyl)-[1,3,2]-dioxaborolane

: 1016641-70-5
4,4,5,5-tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

Guidance literature:: With dichlorodioxobis(triphenylphosphineoxide)molybdenum(VI); tetrabutylammonium nitrate; copper(II) nitrate; In acetonitrile; at 60 ℃; for 10h; chemoselective reaction;
DOI:10.1021/jo2001808

Reference yield:

: 934-71-4
1-bromo-4-(methylsulfinyl)benzene

: 73183-34-3
bis(pinacol)diborane

: 1016641-70-5
4,4,5,5-tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

Guidance literature:: With potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In 1,4-dioxane; at 85 ℃; for 4h;

Reference yield:

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 98546-51-1
(4-thiomethoxyphenyl)boronic acid

: 1016641-70-5
4,4,5,5-tetramethyl-2-(4-(methylsulfinyl)phenyl)-1,3,2-dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1.1: toluene / Reflux

1.2: 2 h / Molecular sieve; Heating

2.1: dichlorodioxobis(triphenylphosphineoxide)molybdenum(VI); tetrabutylammonium nitrate; copper(II) nitrate / acetonitrile / 10 h / 60 °C

With dichlorodioxobis(triphenylphosphineoxide)molybdenum(VI); tetrabutylammonium nitrate; copper(II) nitrate; In toluene; acetonitrile;
DOI:10.1021/jo2001808