3-Bromo-6-hydroxy-2-methylbenzaldehyde

Base Information

Chemical Name:3-Bromo-6-hydroxy-2-methylbenzaldehyde
CAS No.:137644-94-1
Molecular Formula:C8H7BrO2
Molecular Weight:215.046
Hs Code.:
European Community (EC) Number:843-162-5
DSSTox Substance ID:DTXSID60577021
Wikidata:Q82466935
Mol file:137644-94-1.mol

Synonyms:3-BROMO-6-HYDROXY-2-METHYLBENZALDEHYDE;137644-94-1;SCHEMBL1390662;DTXSID60577021;GYSFTNVHSLJTCO-UHFFFAOYSA-N;MFCD21607420;3-Bromo-6-hydroxy-2-methyl-benzaldehyde;WS-01990;EN300-338289;Z1416194984

Suppliers and Price of 3-Bromo-6-hydroxy-2-methylbenzaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3-Bromo-6-hydroxy-2-methylbenzaldehyde

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:213.96294
Heavy Atom Count:11
Complexity:149

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C=CC(=C1C=O)O)Br

Technology Process of 3-Bromo-6-hydroxy-2-methylbenzaldehyde

There total 5 articles about 3-Bromo-6-hydroxy-2-methylbenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 137644-93-0
3-bromo-6-methoxy-2-methylbenzaldehyde

: 137644-94-1
3-bromo-6-hydroxy-2-methylbenzaldehyde

Guidance literature:: With boron tribromide; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1039/P19910002565

Reference yield:

: 54884-55-8
2-methoxy-6-methyl-benzaldehyde

: 137644-94-1
3-bromo-6-hydroxy-2-methylbenzaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / Br₂, iron / CCl₄ / 0.75 h / -10 °C

2: 91 percent / boron tribromide / CH₂Cl₂ / 1 h / 0 °C

With bromine; boron tribromide; iron; In tetrachloromethane; dichloromethane;
DOI:10.1039/P19910002565

Reference yield:

: 6161-65-5
2-methoxy-6-methyl-benzoic acid

: 137644-94-1
3-bromo-6-hydroxy-2-methylbenzaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: thionyl chloride / tetrahydrofuran / 6 h / 50 °C / Cooling with ice

2: lithium aluminium tetrahydride / tetrahydrofuran / 5 h / 25 °C

3: Dess-Martin periodane / dichloromethane / 8 h / 25 °C

4: bromine; iron / tetrachloromethane / 1 h / 0 °C

5: boron tribromide / dichloromethane / 3 h / 25 °C

With lithium aluminium tetrahydride; thionyl chloride; bromine; boron tribromide; iron; Dess-Martin periodane; In tetrahydrofuran; tetrachloromethane; dichloromethane;