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| CAS No.: | 57-50-1 |
|---|---|
| Name: | Sucrose |
| Molecular Structure: | |
|
|
|
| Formula: | C12H22O11 |
| Molecular Weight: | 342.3 |
| Synonyms: | Sucrose(8CI);(+)-Sucrose;Amerfond;Beet sugar;Cane sugar;Carrare C 10;Confectioner's sugar;Frost Sugar;GNE 410;Granulated sugar;Khandsari;Manalox AS;Microse;NSC 406942;Rockcandy;Saccharose;Saccharum;Sucrose NF;Sugar;White sugar;a-D-Glucosyl-b-D-fructofuranoside;b-D-Fructofuranosyl a-D-glucopyranoside; |
| EINECS: | 200-334-9 |
| Density: | 1.77 g/cm3 |
| Melting Point: | 185-187 °C(lit.) |
| Boiling Point: | 697.1 °C at 760 mmHg |
| Flash Point: | 375.4 °C |
| Solubility: | 1970 g/L (15 ºC) |
| Appearance: | White crystalline powder |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 24/25-37/39-26 |
| PSA: | 189.53000 |
| LogP: | -5.39560 |
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- 57-50-1
Sucrose
| Conditions | Yield |
|---|---|
| With Amberlite IR-45(OH-); hydrogen; palladium on activated charcoal In methanol; ethyl acetate under 5688.78 Torr; | 100% |
| Conditions | Yield |
|---|---|
| magnesium oxide In methanol for 1h; Ambient temperature; | 90% |
| With sodium methylate In methanol at 20℃; for 3h; Inert atmosphere; | 90% |
| With methanol; potassium cyanide for 0.5h; Ambient temperature; | 75% |
| Conditions | Yield |
|---|---|
| With niobic acid In water at 89.84℃; for 2h; Catalytic behavior; Reagent/catalyst; Autoclave; Inert atmosphere; | A 87% B n/a |
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tetra-O-benzyl-α-D-galactosyl bromide
| Conditions | Yield |
|---|---|
| With tetrahexylammonium bromide In N,N-dimethyl-formamide; toluene for 72h; Ambient temperature; | A 74% B 8.2% |
| Conditions | Yield |
|---|---|
| With hydrogen In water at 89.84℃; under 15001.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Pressure; | A 41% B 43% C 6% |
| With hydrogen In water at 89.84℃; under 15001.5 Torr; for 4h; | A 37% B 36% C 8.4% |
| Conditions | Yield |
|---|---|
| With hydrogen In water at 89.84℃; under 15001.5 Torr; for 4h; | A 8.5% B 40% C 39% D 5.5% |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 130℃; for 6h; pH=8; pH-value; Inert atmosphere; Sealed tube; | A 11.8% B 10.1% |
| Conditions | Yield |
|---|---|
| mit Hilfe von Enzym-Praeparaten aus Weizenkeimen oder gruenen Erbsen; | |
| Biosynthese mit Hilfe von Sucrosesynthase aus Weizenkeimen; | |
| With sucrose synthase In aq. phosphate buffer at 37℃; for 1h; pH=8.5; Enzymatic reaction; |
| Conditions | Yield |
|---|---|
| at 100℃; im Vakuum; |
| Conditions | Yield |
|---|---|
| With sodium periodate; ethanol; water anschl. mit wss. Na2CO3; |
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Chemistry
Structure of D(+)-Sucrose (CAS NO.57-50-1):
Empirical Formula: C12H22O11
Molecular Weight: 342.2965
Nominal Mass: 342 Da
Average Mass: 342.2965 Da
Monoisotopic Mass: 342.116212 Da
Index of Refraction: 1.656
Molar Refractivity: 70.85 cm3
Molar Volume: 192.8 cm3
Surface Tension: 113 dyne/cm
Density: 1.77 g/cm3
Flash Point: 375.4 °C
Enthalpy of Vaporization: 116.71 kJ/mol
Boiling Point: 697.1 °C at 760 mmHg
Vapour Pressure: 1.79E-22 mmHg at 25 °C
Melting point: 185-187 °C(lit.)
Storage tempreture: Store at RT.
Water solubility: 500 mg/mL
Appearance: White odorless crystalline or powdery solid
IUPAC Name: (2R,3R,4S,5S,6R)-2-[(2S,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol
Canonical SMILES: C(C1C(C(C(C(O1)OC2(C(C(C(O2)CO)O)O)CO)O)O)O)O
Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)O[C@]2([C@H]([C@@H]([C@H](O2)CO)O)O)CO)O)O)O)O
InChI: InChI=1S/C12H22O11/c13-1-4-6(16)8(18)9(19)11(21-4)23-12(3-15)10(20)7(17)5(2-14)22-12/h4-11,13-20H,1-3H2/t4-,5-,6-,7-,8+,9-,10+,11-,12+/m1/s1
InChIKey: CZMRCDWAGMRECN-UGDNZRGBSA-N
Product Category of 4-Chloro-6,7-bis(2-methoxyethoxy)quinazoline (CAS NO.183322-18-1):
Oligosaccharide Compounds;Basic Sugars (Mono & Oligosaccharides);Biochemistry;Disaccharides;Sugars;Oligosaccharides
Uses
D(+)-Sucrose (CAS NO.57-50-1) can be widely used in food, cosmetics, and medicine, and is also used for the analysis of standard testing. It has been used as the standard for organic elemental analysis, too.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| domestic animals - goat/sheep | LDLo | oral | 40gm/kg (40000mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Nutrition Abstracts and Reviews. Vol. 30, Pg. 503, 1960. |
| mouse | LD50 | intraperitoneal | 14000mg/kg (14000mg/kg) | Pharmaceutical Chemistry Journal Vol. 15, Pg. 139, 1981. | |
| rat | LD50 | oral | 29700mg/kg (29700mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: CYANOSIS GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Toxicology and Applied Pharmacology. Vol. 7, Pg. 609, 1965. |
Consensus Reports
Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
Safety Profile
Mildly toxic by ingestion. An experimental teratogen. Mutation data reported. Vigorous reaction with nitric acid or sulfuric acid (forms carbon monoxide and carbon dioxide). When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: 
Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25-37/39-26
S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
Standards and Recommendations
OSHA PEL: TWA Total Dust: 15 mg/m3; Respirable Fraction: 5 mg/m3
ACGIH TLV: TWA (nuisance particulate) 10 mg/m3 of total dust (when toxic impurities are not present, e.g., quartz <1%); Not Classifiable as a Human Carcinogen
NIOSH REL: (Sucrose, Respirable Fraction) TWA 5 mg/m3; (Sucrose, total dust): TWA 10 mg/m3
Specification
D(+)-Sucrose , its cas register number is 57-50-1. It also can be called alpha-D-Glucopyranosyl beta-D-fructofuranoside ; beta-D-Fructofuranose-(2-1)-alpha-D-glucopyranoside ; Sucrose ; Saccharose ; and alpha-D-Glucopyranosyl beta-D-fructofuranoside . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: Should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. While, it's inhaled: Remove from exposure and move to fresh air immediately. Then you have the ingesting of the product: Wash mouth out with water. Notes to physician: Treat supportively and symptomatically.
In addition, D(+)-Sucrose (CAS NO.57-50-1) could be stable under normal temperatures and pressures. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide.