N-ALLYL-BENZENE-1,3-DIAMINE

Base Information

• Chemical Name: N-ALLYL-BENZENE-1,3-DIAMINE
• CAS No.: 34884-70-3
• Molecular Formula: C9H12N2
• Molecular Weight: 148.208
• Hs Code.: 2921590090
• Mol file: 34884-70-3.mol

Synonyms:N-ALLYL-BENZENE-1,3-DIAMINE

Chemical Property of N-ALLYL-BENZENE-1,3-DIAMINE

Chemical Property:

• Vapor Pressure: 0.000832mmHg at 25°C
• Boiling Point: 305.2°C at 760 mmHg
• Flash Point: 161.4°C
• PSA: 38.05000
• Density: 1.064g/cm³
• LogP: 2.52090

Purity/Quality:

99% ^*data from raw suppliers

N-ALLYL-BENZENE-1,3-DIAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-ALLYL-BENZENE-1,3-DIAMINE

There total 6 articles about N-ALLYL-BENZENE-1,3-DIAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-amino-2-propene (107-11-9,30551-89-4) + 3-Iodoaniline (626-01-7) → N-allyl-benzene-1,3-diamine (34884-70-3)

Guidance literature:

With 2-(2-methyl-1-oxopropane)cyclohexanone; caesium carbonate; copper(l) iodide; In N,N-dimethyl-formamide; at 20 ℃; for 6h;

DOI:10.1021/ja063063b

Reference yield: 84.0%

1-amino-2-propene (107-11-9,30551-89-4) + m-Bromoaniline (591-19-5) → N-allyl-benzene-1,3-diamine (34884-70-3)

Guidance literature:

With potassium phosphate; copper(l) iodide; L-proline; In dimethyl sulfoxide; at 90 ℃; for 40h;

DOI:10.1021/jo0504464

Reference yield:

allyl bromide (106-95-6) + m-acetamide aniline (102-28-3) → N-(3-(diallylamino)phenyl)acetamide (69962-41-0) + N-allyl-benzene-1,3-diamine (34884-70-3)

Guidance literature:

allyl bromide; m-acetamide aniline; With potassium carbonate; In ethanol; water; at 70 ℃; for 0.24h;

With hydrogenchloride; In tetrahydrofuran; water; at 70 ℃; for 15h;

upstream raw materials:

N-allyl-(3-nitrophenyl)amine

1-amino-2-propene

m-Bromoaniline

3-Iodoaniline

Refernces

• 1、 -. "COLORED CHARGED SILSESQUIOXANES". Paragraph 0885; 1062; 1064; 1068-1069. . Retrieved 2018/02/10.
• 2、 Zhang, Hui,Cai, Qian,Ma, Dawei. "Amino acid promoted CuI-catalyzed C-N bond formation between aryl halides and amines or N-containing heterocycles". . p. 5164 - 5173. Retrieved 2007/10/03.