1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol

Base Information

• Chemical Name: 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol
• CAS No.: 18779-57-2
• Molecular Formula: C₁₈H₂₄O₁₂
• Molecular Weight: 432.381
• Mol file: 18779-57-2.mol

Synonyms:1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol;muco-Inositol hexaacetate

Chemical Property of 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol

There total 17 articles about 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,4-bis-O-tert-butyldiphenylsilyl-L-muco-inositol + acetic anhydride (108-24-7) → 1,2,3,4,5,6-hexa-O-acetyl-muco-inositol (18779-57-2)

Guidance literature:

1,4-bis-O-tert-butyldiphenylsilyl-L-muco-inositol; With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 5h; Inert atmosphere; Cooling with ice;

acetic anhydride; With pyridine; dmap; at 50 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c7cc01191a

Reference yield: 74.0%

acetic anhydride (108-24-7) + L-4-O-benzyl-3-O-1,2-O-(2,2,2-trichloroethylidene)-3-O-cyclohexylcarbamoyl-5-O-methyl-muco-inositol (402724-04-3) → 3,4,5,6-tetra-O-acetyl-1,2-O-(2,2,2-trichloroethylidene)-muco-inositol + 1,2,3,4,5,6-hexa-O-acetyl-muco-inositol (18779-57-2)

Guidance literature:

L-4-O-benzyl-3-O-1,2-O-(2,2,2-trichloroethylidene)-3-O-cyclohexylcarbamoyl-5-O-methyl-muco-inositol; With hydrogen iodide; In water; for 2h; Heating;

acetic anhydride; With pyridine; at 20 ℃; for 12h;

DOI:10.1016/j.carres.2004.11.031

Reference yield: 60.0%

acetic anhydride (108-24-7) + 1,2,3,6-tetra-O-acetyl-muco-inositol (113973-61-8) → 1,2,3,4,5,6-hexa-O-acetyl-muco-inositol (18779-57-2)

Guidance literature:

With zinc(II) chloride; In chloroform; for 2h;

DOI:10.1016/0008-6215(87)80140-4

upstream raw materials:

Perbenzoic acid

chloroform

(+/-)-Conduritol F

acetic acid

Downstream raw materials:

muco-inositol