1,4-Anthracenedicarboxylic acid dimethyl ester

Base Information

• Chemical Name: 1,4-Anthracenedicarboxylic acid dimethyl ester
• CAS No.: 58791-46-1
• Molecular Formula: C₁₈H₁₄O₄
• Molecular Weight: 294.307
• Mol file: 58791-46-1.mol

Synonyms:1,4-Anthracenedicarboxylic acid dimethyl ester

Chemical Property of 1,4-Anthracenedicarboxylic acid dimethyl ester

Chemical Property:

• PSA: 52.60000
• LogP: 3.56620

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-Anthracenedicarboxylic acid dimethyl ester

There total 4 articles about 1,4-Anthracenedicarboxylic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9,10-dioxo-9,10-dihydro-1,4-anthracene dicarboxylic acid (54292-11-4) → 1,4-Anthracendicarbonsaeure-dimethylester (58791-46-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 49 percent / Zn, NH₄OH / 80 °C

2: K₂CO₃ / butan-2-one / Heating

With ammonium hydroxide; potassium carbonate; zinc; In butanone;

DOI:10.1016/S0960-894X(97)10207-4

Reference yield:

methanol (67-56-1) + 1,4-anthracenedicarboxylic acid (58791-45-0) → 1,4-Anthracendicarbonsaeure-dimethylester (58791-46-1)

Guidance literature:

With sulfuric acid;

Reference yield:

1,4-anthracenedicarboxylic acid (58791-45-0) + dimethyl sulfate (77-78-1) → 1,4-Anthracendicarbonsaeure-dimethylester (58791-46-1)

Guidance literature:

With potassium carbonate; In butanone; Yield given; Heating;

DOI:10.1016/S0960-894X(97)10207-4

upstream raw materials:

methanol

1,4-anthracenedicarboxylic acid

dimethyl sulfate

9,10-dioxo-9,10-dihydro-1,4-anthracene dicarboxylic acid

Refernces

• 1、 Iyengar, Bhashyam S.,Dorr, Robert T.,Alberts, David S.,Sólyom, Anikó M.,Krutzsch, Mary,Remers, William A.. "1,4-disubstituted anthracene antitumor agents". . p. 3734 - 3738. Retrieved 2007/10/03.