Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate

Base Information

Chemical Name:Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate
CAS No.:1762-46-5
Molecular Formula:C16H16N2O4
Molecular Weight:300.314
Hs Code.:2933399090
European Community (EC) Number:835-744-2
DSSTox Substance ID:DTXSID40481354
Nikkaji Number:J854.731I
Wikidata:Q82316709
Mol file:1762-46-5.mol

Synonyms:1762-46-5;Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate;Diethyl 2,2'-bipyridine-5,5'-dicarboxylate;Diethyl bipy55'DC;C16H16N2O4;ethyl 6-(5-ethoxycarbonylpyridin-2-yl)pyridine-3-carboxylate;MFCD11110569;[2,2'-Bipyridine]-5,5'-dicarboxylic acid, 5,5'-diethyl ester;5,5'-DIETHYL [2,2'-BIPYRIDINE]-5,5'-DICARBOXYLATE;IUNBUYCOAQHBMC-UHFFFAOYSA-N;5,5'-Bis(ethoxycarbonly)-2,2'-Bipyridine;AGN-PC-0NI5SB;YSWG815;SCHEMBL811649;DTXSID40481354;BAA76246;AKOS022174906;Diethyl bipyridine-5,5'-dicarboxylate;DS-7538;SY100883;CS-0066769;D5295;diethyl-2,2'-bipyridine-5,5'-dicarboxylate;C73357;Diethyl[2,2'-bipyridine]-5,5'-dicarboxylate;A911629;J-400864;Diethyl [2,2 inverted exclamation mark -Bipyridine]-5,5 inverted exclamation mark -dicarboxylate

Suppliers and Price of Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate
1G
$ 297.00

TCI Chemical
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate
200MG
$ 89.00

Chem-Impex
Diethyl[2,2'-Bipyridine]-5,5'-dicarboxylate,≥98%(GC) ≥98%(GC)
200MG
$ 92.02

Chem-Impex
Diethyl[2,2'-Bipyridine]-5,5'-dicarboxylate,98%(GC) 98%(GC)
1G
$ 342.72

Chemenu
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate 95%
10g
$ 96.00

Arctom
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate 97%
5g
$ 252.00

Arctom
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate 97%
250mg
$ 37.00

Arctom
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate 97%
1g
$ 73.00

Arctom
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate 97%
100mg
$ 23.00

Ambeed
Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate 97%
1g
$ 74.00

Total 23 raw suppliers

Chemical Property of Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate

Chemical Property:

Melting Point:145-147 °C
Boiling Point:428.9±45.0 °C(Predicted)
PKA:1.99±0.32(Predicted)
Flash Point:213.21oC
PSA：78.38000
Density:1.201±0.06 g/cm3(Predicted)
LogP:2.49700
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:7
Exact Mass:300.11100700
Heavy Atom Count:22
Complexity:352

Purity/Quality:

99%, ^*data from raw suppliers

Diethyl [2,2'-Bipyridine]-5,5'-dicarboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CN=C(C=C1)C2=NC=C(C=C2)C(=O)OCC

Technology Process of Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate

There total 10 articles about Diethyl [2,2'-bipyridine]-5,5'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 64-17-5
ethanol

: 1802-30-8
2,2'-bipyridine-5,5'-dicarboxylic acid

: 1762-46-5
[2,2']bipyridinyl-5,5'-dicarboxylic acid diethyl ester

Guidance literature:: With sulfuric acid; at 80 ℃; for 12h;
DOI:10.1021/acs.inorgchem.6b02474

Reference yield: 93.0%

: 1802-30-8
2,2'-bipyridine-5,5'-dicarboxylic acid

: 1762-46-5
[2,2']bipyridinyl-5,5'-dicarboxylic acid diethyl ester

Guidance literature:: With sulfuric acid; In ethanol; for 18h; Reflux;
DOI:10.1002/chem.201301629

Reference yield: 84.0%

: 151917-39-4
ethyl 6-iodonicotinate

: 1762-46-5
[2,2']bipyridinyl-5,5'-dicarboxylic acid diethyl ester

Guidance literature:: With palladium diacetate; potassium carbonate; In N,N-dimethyl-formamide; isopropyl alcohol; at 100 ℃; for 6h;
DOI:10.3762/bjoc.11.9