(1-Butyl-2,4-cyclopentadien-1-YL)trimethylsilane

Base Information

• Chemical Name: (1-Butyl-2,4-cyclopentadien-1-YL)trimethylsilane
• CAS No.: 208242-21-1
• Molecular Formula: C₁₂H₂₂Si
• Molecular Weight: 194.392
• DSSTox Substance ID: DTXSID60699378
• Mol file: 208242-21-1.mol

Synonyms:208242-21-1;(1-BUTYL-2,4-CYCLOPENTADIEN-1-YL)TRIMETHYLSILANE;DTXSID60699378;AKOS006287224;5-Butyl-5-(Trimethylsilyl)-1,3-cyclopentadiene;J-517225;(1-Butylcyclopenta-2,4-dien-1-yl)(trimethyl)silane;(1-BUTYLCYCLOPENTA-2,4-DIEN-1-YL)TRIMETHYLSILANE

Chemical Property of (1-Butyl-2,4-cyclopentadien-1-YL)trimethylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 4.38120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 194.149077236
• Heavy Atom Count: 13
• Complexity: 206

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC1(C=CC=C1)[Si](C)(C)C

Technology Process of (1-Butyl-2,4-cyclopentadien-1-YL)trimethylsilane

There total 2 articles about (1-Butyl-2,4-cyclopentadien-1-YL)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium cyclopentadienylide (4984-82-1) → (1-Butyl-cyclopenta-2,4-dienyl)-trimethyl-silane (208242-21-1)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether / 0 deg C, 30 min, then room temp., 20 h

2: 1.) methyllithium / diethyl ether / 1.) room temp., 5 h; 2.) 0 deg C, 30 min, then -> room temp., overnight

With methyllithium; In diethyl ether;

DOI:10.1016/S0022-328X(97)00735-3

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1-(n-C4H9)C5H5 (78347-54-3) → (1-Butyl-cyclopenta-2,4-dienyl)-trimethyl-silane (208242-21-1)

Guidance literature:

With methyllithium; In diethyl ether; Yield given; 1.) room temp., 5 h; 2.) 0 deg C, 30 min, then -> room temp., overnight;

DOI:10.1016/S0022-328X(97)00735-3

upstream raw materials:

chloro-trimethyl-silane

1-(n-C₄H₉)C₅H₅

sodium cyclopentadienylide