4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)phenol

Base Information

Chemical Name:4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)phenol
CAS No.:937591-48-5
Molecular Formula:C13H19BO4
Molecular Weight:250.102
Hs Code.:2934999090
DSSTox Substance ID:DTXSID30587819
Nikkaji Number:J3.642.441I
Wikidata:Q82480312
Mol file:937591-48-5.mol

Synonyms:4-METHOXY-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL;937591-48-5;SCHEMBL4521109;DTXSID30587819;MFCD10699454;AKOS027393562;DM-0780;MB08857;CS-0175517;E90377;1-Hydroxy-4-methoxybenzene-2-boronic Acid Pinacol Ester

Suppliers and Price of 4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)phenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

ChemBridge Corporation
4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 95%
10 g
$ 1760.00

AOBChem
4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 95%
1g
$ 285.00

Total 4 raw suppliers

Chemical Property of 4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)phenol

Chemical Property:

PSA：47.92000
LogP:1.70000
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:250.1376392
Heavy Atom Count:18
Complexity:289

Purity/Quality:

99% ^*data from raw suppliers

4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=C(C=CC(=C2)OC)O

Technology Process of 4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)phenol

There total 11 articles about 4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 150-76-5
4-methoxy-phenol

: 73183-34-3
bis(pinacol)diborane

: 937591-48-5
4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

Guidance literature:: bis(pinacol)diborane; With C₂₄H₂₈ClIrN₂O; In tetrahydrofuran; at 65 ℃; for 1h; Sealed tube; Inert atmosphere;

4-methoxy-phenol; In tetrahydrofuran; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.orglett.0c04210

Reference yield: 31.0%

: 17332-11-5
2-bromo-4-methoxyphenol

: 1195-66-0
2-methoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 937591-48-5
4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

: 150-76-5
4-methoxy-phenol

Guidance literature:: 2-bromo-4-methoxyphenol; With n-butyllithium; In tetrahydrofuran; at -78 - 0 ℃; for 1.25h; Inert atmosphere;

2-methoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201303659

Reference yield:

: 17332-11-5
2-bromo-4-methoxyphenol

: 73183-34-3
bis(pinacol)diborane

: 937591-48-5
4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

Guidance literature:: With 1,1'-bis-(diphenylphosphino)ferrocene; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; In 1,4-dioxane; at 80 ℃; Inert atmosphere;