(4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester

Base Information

Chemical Name:(4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester
CAS No.:106757-55-5
Molecular Formula:C₉H₁₄O₄
Molecular Weight:186.208
Hs Code.:
European Community (EC) Number:600-769-8
DSSTox Substance ID:DTXSID901171784
Nikkaji Number:J303.042C
Mol file:106757-55-5.mol

Synonyms:106757-55-5;r-methyl 3-(2,2-dimethyl 1,3-dioxolane-4-yl)-trans-2-propenoate;(4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester;methyl (2E)-3-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate;methyl (E)-3-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate;SCHEMBL4092900;VXZZSPHSNBVYHV-SMMXGFFBSA-N;DTXSID901171784;AKOS006309841;Methyl (2E)-3-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-propenoate

Suppliers and Price of (4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of (4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester

Chemical Property:

Vapor Pressure:0.012mmHg at 25°C
Boiling Point:260.961°C at 760 mmHg
Flash Point:95.556°C
PSA：44.76000
Density:1.128g/cm³
LogP:0.86710
XLogP3:0.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:186.08920892
Heavy Atom Count:13
Complexity:220

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(OCC(O1)C=CC(=O)OC)C
Isomeric SMILES:CC1(OC[C@H](O1)/C=C/C(=O)OC)C

Technology Process of (4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester

There total 11 articles about (4R,alphaE)-2,2-Dimethyl-1,3-dioxolane-4-acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 22323-80-4
(4S)-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde

: 106757-55-5
(E)-3-((R)-2,2-dimethyl[1,3]-dioxolan-4-yl)acrylic acid methyl ester

: 106757-56-6
(Z)-(-)-methyl 3-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate

Guidance literature:: In methanol; at 0 ℃; for 1h;
DOI:10.1016/0008-6215(92)84186-V

Reference yield: 16.4%

: 1779-58-4
(methyloxycarbonylmethyl)triphenylphosphonium bromide

: 22323-80-4
(4S)-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde

: 106757-55-5
(E)-3-((R)-2,2-dimethyl[1,3]-dioxolan-4-yl)acrylic acid methyl ester

: 106757-56-6
(Z)-(-)-methyl 3-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate

Guidance literature:: With sodium hydride; In 1,2-dimethoxyethane; pentane; for 2h; Ambient temperature;

Reference yield:

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 14347-78-5,36543-79-0
1,2-O-isopropylidene-D-glycerol

: 106757-55-5
(E)-3-((R)-2,2-dimethyl[1,3]-dioxolan-4-yl)acrylic acid methyl ester

: 106757-56-6
(Z)-(-)-methyl 3-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate

Guidance literature:: 1,2-O-isopropylidene-D-glycerol; With N-Bromosuccinimide; 4-acetoxy-2,2,6,6-tetramethylpiperidine-1-oxyl; sodium hydrogencarbonate; In tetrahydrofuran; at 10 ℃;

methyl (triphenylphosphoranylidene)acetate; In tetrahydrofuran; at 0 ℃; for 16h;