Apo-12'-lycopenal

Base Information

Chemical Name:Apo-12'-lycopenal
CAS No.:1071-52-9
Molecular Formula:C₂₅H₃₄O
Molecular Weight:350.544
Hs Code.:
Mol file:1071-52-9.mol

Synonyms:Apo-12'-lycopenal;(2E,4E,6E,8E,10E,12E,14E)-2,7,11,15,19-Pentamethyl-2,4,6,8,10,12,14,18-eicosaoctaenal

Suppliers and Price of Apo-12'-lycopenal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AvaChem
Apo-12
2mg
$ 390.00

AvaChem
Apo-12
5mg
$ 590.00

Arctom
Apo-12’-lycopenal ≥95%
5mg
$ 534.55

Total 21 raw suppliers

Chemical Property of Apo-12'-lycopenal

Chemical Property:

Melting Point:105-106 °C
Boiling Point:506.7±19.0 °C(Predicted)
PSA：17.07000
Density:0.907±0.06 g/cm3(Predicted)
LogP:7.38550

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

Apo-12 ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Apo-12'-lycopenal

There total 17 articles about Apo-12'-lycopenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 5056-17-7
(2E,4E,6E)-2,7-dimethyl-2,4,6-octatrienedial

: 131801-83-7
[3,7,11-trimethyl-dodecyl-2,4,6,10-tetraenyl]-triphenylphosphonium chloride

: 103956-99-6,1071-52-9
(2E,4E,6E,8E,10E,12E,14E)-2,7,11,15,19-pentamethylicosa-2,4,6,8,10,12,14,18-octaenal

Guidance literature:: With sodium methylate; In dichloromethane; at 0 ℃; for 0.166667h;
DOI:10.1002/hlca.19920750611

Reference yield: 23.2%

: 502-65-8
lycopene

: 103956-99-6,1071-52-9
(2E,4E,6E,8E,10E,12E,14E)-2,7,11,15,19-pentamethylicosa-2,4,6,8,10,12,14,18-octaenal

: (4E,6E,8E,10E,12E,14E,16E,18E,20E,22E)-2,6,10,15,19,23,27-heptamethyloctacosa-2,4,6,8,10,12,14,16,18,20,22,26-dodecaene

: (2E,4E,6E,8E,10E,12E,14E,16E,18E)-2,6,11,15,19-pentamethyldocosa-2,4,6,8,10,12,14,16,18-nonaenedial

: (4E,6E,8E,10E,12E,14E,16E)-4,8,12,17-tetramethyl-18-oxononadeca-4,6,8,10,12,14,16-heptaenal

: (2E,4E,6E,8E,10E,12E,14E,16E)-2,6,11,15-tetramethyloctadeca-2,4,6,8,10,12,14,16-octaenedial

Guidance literature:: With potassium permanganate; cetyltrimethylammonim bromide; In dichloromethane; water; toluene; at 26 ℃; for 0.5h;
DOI:10.1021/acs.jafc.8b04850

Reference yield:

: 141-10-6,3548-78-5
pseudoionone

: 103956-99-6,1071-52-9
(2E,4E,6E,8E,10E,12E,14E)-2,7,11,15,19-pentamethylicosa-2,4,6,8,10,12,14,18-octaenal

Guidance literature:: Multi-step reaction with 4 steps

1: 1) Li, liq. NH₃ / 2) THF, 10 deg C, 5 min

2: 92 percent / H₂, 2,2'-(ethylenedithio)bis(ethanol), Et₃N / Lindlar catalyst / CH₂Cl₂ / 750.06 Torr / Ambient temperature

3: 1) AcOH, 2) 2percent aq. NaCl / 1) hexane, 60 deg C, 2.5 h, 2) CH₂Cl₂

4: 41 percent / 3M methanol. NaOMe / CH₂Cl₂ / 0.17 h / 0 °C

With 2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol; ammonia; hydrogen; sodium methylate; lithium; acetic acid; triethylamine; sodium chloride; Lindlar's catalyst; In dichloromethane;
DOI:10.1002/hlca.19920750611