R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Base Information

Chemical Name:R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
CAS No.:188055-47-2
Molecular Formula:C26H17O3P
Molecular Weight:408.385141
Hs Code.:
Mol file:188055-47-2.mol

Synonyms:R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-4-Phenoxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Suppliers and Price of R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 9 raw suppliers

Chemical Property of R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Chemical Property:

Storage Temp.:Inert atmosphere,under -40°C

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

There total 1 articles about R-4-phenoxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 137156-22-0,171878-71-0,155613-52-8
binaphthol chlorophosphite

: 108-95-2,27073-41-2
phenol

: 188055-47-2,256441-54-0,1247952-48-2
(S_a)-2-(phenoxy)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine

Guidance literature:: With triethylamine; In tetrahydrofuran; Combinatorial reaction / High throughput screening (HTS);
DOI:10.1021/om300194k

Reference yield: 81.0%

: 37366-09-9
dichloro(benzene)ruthenium(II) dimer

: 1247952-48-2,188055-47-2,256441-54-0
(R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite

: 1247628-76-7,1247628-93-8
[RuCl2(η6-benzene)((R)-PhOP(binaphthoxy))]

Guidance literature:: In CH₂Cl₂; (N2) Ru complex and ligand in CH2Cl2 were stirred at room temp. for 24 h; soln. was filtered and evapd. to dryness, residue was washed with Et2O-hexane (1:3) and vac.-dried;
DOI:10.1039/c0dt00140f

Reference yield: 79.0%

: 52462-29-0
[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

: 1247952-48-2,188055-47-2,256441-54-0
(R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite

: 1247628-82-5,1247629-00-0
[RuCl2(η6-p-cymene)((R)-PhOP(binaphthoxy))]

Guidance literature:: In CH₂Cl₂; (N2) Ru complex and ligand in CH2Cl2 were stirred at room temp. for 1 h; soln. was filtered and evapd. to dryness, residue was washed with Et2O-hexane (1:3) and vac.-dried;
DOI:10.1039/c0dt00140f