5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)

Base Information

• Chemical Name: 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)
• CAS No.: 57715-41-0
• Molecular Formula: C₄₈H₃₆FeN₄O₄
• Molecular Weight: 788.685
• Mol file: 57715-41-0.mol

Synonyms:5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)

Chemical Property of 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)

There total 6 articles about 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin + iron(II) chloride → 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II) (57715-41-0)

Guidance literature:

In N,N-dimethyl-formamide; two step procedure: absorbing of metal chloride on RB-carbon carrier followed by reaction with porphin;

DOI:10.1002/bbpc.198800335

Reference yield:

μ-oxo-bis(meso-tetra-p-methoxyphenylporphyrin)iron(III) (37191-17-6) → 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II) (57715-41-0)

Guidance literature:

With ethanethiol; In toluene; for 72h; Inert atmosphere;

DOI:10.1021/ic101469e

Reference yield:

(5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine)iron(III) chloride (333460-15-4,36995-20-7) → 5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II) (57715-41-0)

Guidance literature:

With sodium dithionite; In water; toluene; complex soln. in toluene purged with N2, aq. Na2S2O4 added, shaken for 5 min; toluene layer dried (Na2SO4), not isolated, detected by UV;

DOI:10.1021/ja00372a003

upstream raw materials:

(5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine)iron(III) chloride

iron(III) chloride

C₄₈H₃₇FeN₄O₄S

μ-oxo-bis(meso-tetra-p-methoxyphenylporphyrin)iron(III)

Downstream raw materials:

(meso-tetra-p-methoxyphenylporphyrin)(2-methylimidazole)iron(II)

(meso-tetra-p-methoxyphenylporphyrin)(1,2-dimethylimidazole)iron(II)