citralva

Base Information

• Chemical Name: citralva
• CAS No.: 80748-12-5
• Molecular Formula: C₁₀H₁₅N
• Molecular Weight: 149.236
• Mol file: 80748-12-5.mol

Synonyms:Einecs 225-918-0

Chemical Property of citralva

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of citralva

There total 31 articles about citralva which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

geraniol (624-15-7) → geranonitrile (5146-66-7,80748-12-5)

Guidance literature:

With ammonia; oxygen; In tert-Amyl alcohol; water; at 100 ℃; for 24h; under 3750.38 Torr; Autoclave; High pressure;

DOI:10.1021/acscatal.0c00485

Reference yield: 96.0%

citral dimethylhydrazone (334475-34-2) → N-methylmethyleneamine N-oxide (54125-41-6) + (Z)-3,7-dimethyl-2,6-octadiene nitrile (31983-27-4,80748-12-5)

Guidance literature:

With dihydrogen peroxide; methyltrioxorhenium(VII); In ethanol; at -50 - 20 ℃; for 1h;

DOI:10.1039/a804839h

Reference yield: 90.0%

(E/Z)-3,7-dimethyl-2,6-octadienal (5392-40-5,96680-15-8) → geranonitrile (5146-66-7,80748-12-5)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; acetylhydroxamic acid; In acetonitrile; for 14h; Reflux;

DOI:10.1016/j.tetlet.2012.04.057

upstream raw materials:

3,7-dimethylocta-2,6-dienal oxime

6-Methyl-hept-5-en-2-on

cyanoacetic acid

(E/Z)-3,7-dimethyl-2,6-octadienal

Downstream raw materials:

2,6,6-trimethyl-2-cyclohexenecarbonitrile

2-cyano-1,1-dimethyl-3-methylenecyclohexane

2,6,6-trimethylcyclohexa-1,3-dienecarbonitrile

2,6,6-trimethyl-4-hydroxy-1-cyclohexene-1-carboxaldehyde

Refernces

• 1、 Achard, Thierry,Bellemin-Laponnaz, Stéphane,Chen, Weiguang,Egly, Julien,Maisse-Francois, Aline,Poblador-Bahamonde, Amalia I.. "Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (κ2-: C, S)-thioether-functionalised NHC ligands". supporting information. p. 3243 - 3252. Retrieved 2020/03/19.
• 2、 Utsumi, Tatsuki,Noda, Kenta,Kawauchi, Daichi,Ueda, Hirofumi,Tokuyama, Hidetoshi. "Nitrile Synthesis by Aerobic Oxidation of Primary Amines and in situ Generated Imines from Aldehydes and Ammonium Salt with Grubbs Catalyst". supporting information. p. 3583 - 3588. Retrieved 2020/08/05.