CID 53629714

Base Information

• Chemical Name: CID 53629714
• CAS No.: 1888-75-1
• Molecular Formula: C3H7 Li
• Molecular Weight: 50.0296
• Hs Code.: 2931900090
• Nikkaji Number: J199.711D
• Mol file: 1888-75-1.mol

Synonyms:

Chemical Property of CID 53629714

Chemical Property:

• Melting Point: 99-100℃
• Boiling Point: 35-36 °C
• Flash Point: 31 °F
• PSA: 0.00000
• Density: 0.632 g/mL at 25 °C
• LogP: 1.36400
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 50.07077866
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Isopropyllithium solution 0.7 M in pentane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+C
• Hazard Codes: F+,C,N,Xn,F
• Statements: 12-14-20/22-34-67-66-65-51/53-11
• Safety Statements: 16-33-36/37/39-45-62-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li].C[CH]C
• Uses: Isopropyllithium is used in a study of the alkylative ring opening of N-sulfonyl protected aziridines providing amino alcohols and ethers. Used in a study of the alkylative ring opening of N-sulfonyl protected aziridines providing amino alcohols and ethers.

Technology Process of CID 53629714

There total 4 articles about CID 53629714 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isopropyl chloride (75-29-6) → isopropyllithium (1888-75-1)

Guidance literature:

With lithium; Petroleum ether;

Reference yield:

isopropylmagnesium bromide (920-39-8) → isopropyllithium (1888-75-1)

Guidance literature:

With diethyl ether; lithium;

DOI:10.1039/jr9410000323

Reference yield:

(perfluoroprop-1-enyl)benzene (41424-70-8,41500-48-5,345-79-9) → isopropyllithium (1888-75-1) + ((E)-1-Fluoro-3-methyl-2-trifluoromethyl-but-1-enyl)-benzene + ((Z)-1-Fluoro-3-methyl-2-trifluoromethyl-but-1-enyl)-benzene + ((Z)-2,3,3,3-Tetrafluoro-1-isopropyl-propenyl)-benzene

Guidance literature:

at 0 - 20 ℃; Yield given. Yields of byproduct given;

DOI:10.1016/S0022-1139(00)80925-2

upstream raw materials:

isopropyl chloride

isopropylmagnesium bromide

(perfluoroprop-1-enyl)benzene

Downstream raw materials:

2,8-dimethylnonan-5-one

2,5-dimethylhexan-3-one

2,4-Dimethyl-3-pentanone

tert-Butyldiisopropylphosphan