POTASSIUM OCTYLTRIFLUOROBORATE

Base Information

Chemical Name:POTASSIUM OCTYLTRIFLUOROBORATE
CAS No.:329976-79-6
Molecular Formula:C8H17BF3.K
Molecular Weight:220.127
Hs Code.:
Mol file:329976-79-6.mol

Synonyms:POTASSIUM OCTYLTRIFLUOROBORATE;Potassium oct-1-yltrifluoroborate;Potassium octane-1-trifluoroborate

Suppliers and Price of POTASSIUM OCTYLTRIFLUOROBORATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Potassium octyltrifluoroborate
5g
$ 217.00

Sigma-Aldrich
Potassium octyltrifluoroborate
1g
$ 67.00

American Custom Chemicals Corporation
POTASSIUM OCTYLTRIFLUOROBORATE 95.00%
5G
$ 979.90

American Custom Chemicals Corporation
POTASSIUM OCTYLTRIFLUOROBORATE 95.00%
1G
$ 657.31

Total 16 raw suppliers

Chemical Property of POTASSIUM OCTYLTRIFLUOROBORATE

Chemical Property:

Melting Point:74-78℃
PSA：0.00000
LogP:4.19430

Purity/Quality:

98%,99%, ^*data from raw suppliers

Potassium octyltrifluoroborate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Uses Reactant for:? ;Hydrolysis with silica gel and water for preparation of boronic acids and esters1? ;Suzuki-Miyaura cross-coupling2? ;Palladium-catalyzed Suzuki-Miyaura-type cross-coupling reaction with alkenyl bromides3? ;Hydrodeboration reactions4 Reactant for:Hydrolysis with silica gel and water for preparation of boronic acids and estersSuzuki-Miyaura cross-couplingPalladium-catalyzed Suzuki-Miyaura-type cross-coupling reaction with alkenyl bromidesHydrodeboration reactions

Technology Process of POTASSIUM OCTYLTRIFLUOROBORATE

There total 11 articles about POTASSIUM OCTYLTRIFLUOROBORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 17049-49-9
octylmagnesium bromide

: 329976-79-6
potassium trifluoro(n-octyl)borate

Guidance literature:: Trimethyl borate; octylmagnesium bromide; In tetrahydrofuran; at -78 - 0 ℃; for 1.83333h;

With potassium hydrogen difluoride; water; In tetrahydrofuran; at 0 - 20 ℃; for 1.16667h;
DOI:10.1002/anie.201201704

Reference yield: 35.0%

: potassium hydrogen difluoride

: 111-83-1
1-bromo-octane

: methyl borate

: 329976-79-6
potassium trifluoro(n-octyl)borate

Guidance literature:: 1-bromo-octane; With magnesium; In tetrahydrofuran; ethylene dibromide; for 3h; Inert atmosphere; Reflux;

methyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 1h; Inert atmosphere;

potassium hydrogen difluoride; In water; at 0 - 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/acs.orglett.8b02221

Reference yield: 30.0%

: 1279123-63-5
potassium hydrogenfluoride

: 121-43-7,63156-11-6
Trimethyl borate

: 17049-49-9
octylmagnesium bromide

: 329976-79-6
potassium trifluoro(n-octyl)borate

Guidance literature:: With hydrogenchloride; In methanol; diethyl ether; water; Mg compd. added to soln. of B compd. at -65--70°C dropwise within1.5 h, warmed to 20°C within 3 h, hydrolysed with aq. HCl, org. phase sepd., aq. phase extd. with ether, dried with MgSO4, dissolved in MeOH, reacted with aq. B compd.; after 5 min filtered, dried, extd. with hot acetone, solvent removed in vac., dried over P4O10;
DOI:10.1002/1521-3749(200205)628:4<883::AID-ZAAC883>3.0.CO;2-A