[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride

Base Information

Chemical Name:[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride
CAS No.:191654-69-0
Molecular Formula:C₄₈H₄₀Cl₂P₂Pd
Molecular Weight:856.119
Hs Code.:
European Community (EC) Number:695-404-2
Mol file:191654-69-0.mol

Synonyms:191654-69-0;[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;dichloropalladium;Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-kappaP]]dichloro-, (SP-4-2)-;[(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride;[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II)chloride

Suppliers and Price of [(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride
500mg
$ 125.00

Sigma-Aldrich
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride
100mg
$ 42.50

American Custom Chemicals Corporation
[(R)-(+)-2,2'-BIS-(DI-PARA-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE 95.00%
5MG
$ 496.53

Total 1 raw suppliers

Chemical Property of [(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride

Chemical Property:

Melting Point:>300°C
PSA：27.18000
LogP:11.25360
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:7
Exact Mass:854.10171
Heavy Atom Count:53
Complexity:900

Purity/Quality:

98%,99%, ^*data from raw suppliers

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 20/21/22-36/37/38
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.Cl[Pd]Cl
Uses Catalyst for:Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetalStereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactantsStereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzincReactant for:Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes

Technology Process of [(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride

There total 2 articles about [(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13965-03-2
bis-triphenylphosphine-palladium(II) chloride

: 153305-67-0,100165-88-6,99646-28-3
(+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl

: 730961-38-3,215597-19-6,191654-69-0
PdCl2[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]

Guidance literature:: In not given; not isolated;
DOI:10.1016/S0022-328X(03)00700-9

Reference yield:

: 21264-30-2,90243-59-7,14592-56-4
dichloro bis(acetonitrile) palladium(II)

: 153305-67-0,100165-88-6,99646-28-3
(+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl

: 730961-38-3,215597-19-6,191654-69-0
PdCl2[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]

Guidance literature:: In not given;
DOI:10.1016/S0022-328X(03)00700-9

Reference yield: 71.0%

: 730961-38-3,215597-19-6,191654-69-0
Pd((R)-tol-binap)Cl₂

: 7732-18-5
water

: 2923-28-6
silver trifluoromethanesulfonate

: [Pd((R)-tol-binap)(H₂O)2](OTf)2

Guidance literature:: In acetone; byproducts: AgCl; addn. of AgOTf to soln. of Pd-complex, stirring for 5 h at 25°C; filtration off of AgCl, evapn., recrystn. (CH2Cl2:ether);
DOI:10.1021/ja9902827