CID 16043495

Base Information

Chemical Name:CID 16043495
CAS No.:55652-52-3
Molecular Formula:C2H8BBrS
Molecular Weight:154.867
Hs Code.:
European Community (EC) Number:629-410-3
DSSTox Substance ID:DTXSID70581396
Mol file:55652-52-3.mol

Synonyms:55652-52-3;SCHEMBL3283496;DTXSID70581396;PUBCHEM_16043495

Suppliers and Price of CID 16043495

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
mono-Bromoborane Methyl Sulfide Complex
5ml
$ 326.00

TRC
mono-BromoboraneMethylSulfideComplex
5ml
$ 60.00

Sigma-Aldrich
mono-Bromoborane methyl sulfide complex solution 1.0 M in methylene chloride
100ml
$ 206.00

American Custom Chemicals Corporation
MONO-BROMOBORANE METHYL SULFIDE COMPLEX 95.00%
5MG
$ 496.44

Total 14 raw suppliers

Chemical Property of CID 16043495

Chemical Property:

Flash Point:50 °F
PSA：25.30000
Density:1.347 g/mL at 25 °C
LogP:0.90860
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:151.94666
Heavy Atom Count:5
Complexity:4.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

mono-Bromoborane Methyl Sulfide Complex ^*data from reagent suppliers

Safty Information:

Pictogram(s): F,T,C
Hazard Codes:F,T,C
Statements: 11-15-23/24/25-34-40-14/15-67-37
Safety Statements: 16-23-26-36/37/39-45-27-43

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[B]Br.CSC
Uses Reactant for:Substitution reactions for synthesis of N-heterocyclic carbene boranes with boron-heteroatom bondsHydroboration reactionsRegio- and chemoselective brominative cleavage of terminal epoxides

Technology Process of CID 16043495

There total 1 articles about CID 16043495 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29957-59-3
boron tribromide-dimethyl sulfide complex

: 13292-87-0
dimethylsulfide borane complex

: 55652-52-3
bromoborane-dimethyl sulfide complex

Guidance literature:: In benzene; at 60 ℃; for 24h; Inert atmosphere;
DOI:10.1002/anie.201809983

Reference yield: 91.0%

: (R)-{(2R,3R)-2,3-Dihydroxy-3-[((R)-methoxycarbonyl-phenyl-methyl)-carbamoyl]-propionylamino}-phenyl-acetic acid methyl ester

: 55652-52-3
bromoborane-dimethyl sulfide complex

: silver carbonate

: Ag⁽¹⁺⁾*((CH₃OCOCH(C₆H₅)NHCOCHO)2)2B^(1-)=Ag(((CH₃OCOCH(C₆H₅)NHCOCHO)2)2B)

Guidance literature:: In dichloromethane; byproducts: H2, HBr; 1) H2BBr*SMe2 in CH2Cl2, 2) Ag2CO3in MeCN; elem. anal.;
DOI:10.1021/om040017g

Reference yield: 86.0%

: 55652-52-3
bromoborane-dimethyl sulfide complex

: 2664-28-0
1,4-diallylbenzene

: (CH₂)3C₆H₄(CH₂)3BOCH₃

Guidance literature:: With MeOH; In dichloromethane; N2-atmosphere; addn. of H2BrB*SMe2 to olefin, then MeOH addn. (pptn.);
DOI:10.1039/c39940000227