Mg(II) Porphine

Base Information

• Chemical Name: Mg(II) Porphine
• CAS No.: 13007-95-9
• Molecular Formula: C20H12MgN4
• Molecular Weight: 332.647
• Mol file: 13007-95-9.mol

Synonyms:Mg(II) Porphine;MagnesiuM Porphyrin;Magnesium Porphine

Chemical Property of Mg(II) Porphine

Chemical Property:

• Melting Point: >370 °C(Solv: ethanol (64-17-5); water (7732-18-5))
• PSA: 56.30000
• LogP: 1.30830

Purity/Quality:

98%,99%, ^*data from raw suppliers

Magnesium Porphyrin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: MII) Porphine (cas# 13007-95-9) is used in the preparation of metalloporphyrin-doped anti-fouling cathode membrane and has application in microbial fuel cell for wastewater treatment.

Technology Process of Mg(II) Porphine

There total 3 articles about Mg(II) Porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C30H22MgN6 (1391114-90-1) → magnesium(II) porphyrin (13007-95-9)

Guidance literature:

at 200 ℃; for 24h; under 0.0375038 Torr;

DOI:10.1016/j.crci.2013.01.015

Reference yield:

5-formyl-2,2'-dipyrrylmethane (36746-27-7) + magnesium bromide (7789-48-2) → tetraphenylporphinatoMg (13007-95-9)

Guidance literature:

5-formyl-2,2'-dipyrrylmethane; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 20 - 98 ℃; for 0.0833333 - 0.25h;

magnesium bromide; In toluene; at 20 - 135 ℃; for 14 - 20.3333h; Product distribution / selectivity; Heating / reflux;

Reference yield:

di(pyrrol-2-yl)methane (21211-65-4) + magnesium bromide (7789-48-2) + <5,5'-diformyl-2,2'-dipyrryl>methane (4511-34-6) → tetraphenylporphinatoMg (13007-95-9)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 115 ℃; for 36h; Product distribution / selectivity;

upstream raw materials:

di(pyrrol-2-yl)methane

magnesium bromide

<5,5'-diformyl-2,2'-dipyrryl>methane

5-formyl-2,2'-dipyrrylmethane

Downstream raw materials:

porphyrin