Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside

Base Information

Chemical Name:Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside
CAS No.:225241-29-2
Molecular Formula:C18H30O5SSi
Molecular Weight:386.585
Hs Code.:
Mol file:225241-29-2.mol

Synonyms:Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside

Suppliers and Price of Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside

Chemical Property:

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside

There total 4 articles about Phenyl 6-O-[(1,1-dimethylethyl)dimethylsilyl]-1-thio-beta-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 16758-34-2
1-thiophenyl-β-D-galactopyranoside

: 18162-48-6
tert-butyldimethylsilyl chloride

: 225241-29-2
phenyl 6-O-(tert-butyldimethylsilyloxy)-1-thio-β-D-galactopyranoside

Guidance literature:: With triethylamine; N,N-dimethyl-formamide; In acetonitrile; at 20 ℃; for 0.5h; regioselective reaction;
DOI:10.1002/ejoc.201901195

Reference yield:

: 108-98-5
thiophenol

: 225241-29-2
phenyl 6-O-(tert-butyldimethylsilyloxy)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane

2: methanol; sodium methylate

3: pyridine; triethylamine / 21.33 h / -10 - 20 °C / Inert atmosphere

With pyridine; methanol; boron trifluoride diethyl etherate; sodium methylate; triethylamine; In dichloromethane;
DOI:10.1016/j.bmc.2011.03.023

Reference yield:

: 4163-60-4
β-D-galactose peracetate

: 225241-29-2
phenyl 6-O-(tert-butyldimethylsilyloxy)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane

2: methanol; sodium methylate

3: pyridine; triethylamine / 21.33 h / -10 - 20 °C / Inert atmosphere

With pyridine; methanol; boron trifluoride diethyl etherate; sodium methylate; triethylamine; In dichloromethane;
DOI:10.1016/j.bmc.2011.03.023