BENZYL (2,4-DIBROMO-PHENYL) ETHER

Base Information

• Chemical Name: BENZYL (2,4-DIBROMO-PHENYL) ETHER
• CAS No.: 856380-98-8
• Molecular Formula: C13H10Br2O
• Molecular Weight: 342.03
• Hs Code.: 2909309090
• Mol file: 856380-98-8.mol

Synonyms:BENZYL (2,4-DIBROMO-PHENYL) ETHER;4-BENZYLOXY-1,3-DIBROMOBENZENE;1-(Benzyloxy)-2,4-dibroMobenzene

Chemical Property of BENZYL (2,4-DIBROMO-PHENYL) ETHER

Chemical Property:

• PSA: 9.23000
• LogP: 4.79060
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

1-(Benzyloxy)-2,4-dibromobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BENZYL (2,4-DIBROMO-PHENYL) ETHER

There total 5 articles about BENZYL (2,4-DIBROMO-PHENYL) ETHER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,4-dibromophenol (615-58-7) + benzyl bromide (100-39-0) → 1-(benzyloxy)-2,4-dibromobenzene (856380-98-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 1.5h; Inert atmosphere;

DOI:10.1016/j.tet.2010.11.054

Reference yield: 90.0%

4-benzyloxybenzyl alcohol (836-43-1) → 1-(benzyloxy)-2,4-dibromobenzene (856380-98-8)

Guidance literature:

With lithium bromide monohydrate; [bis(acetoxy)iodo]benzene; In 2,2,2-trifluoroethanol; at 20 ℃; for 1h; regiospecific reaction;

DOI:10.1055/s-0037-1610980

Reference yield:

benzyl chloride (100-44-7) → 1-(benzyloxy)-2,4-dibromobenzene (856380-98-8) + 2-benzyl-4,6-dibromo-phenol

Guidance literature:

With toluene;

DOI:10.1021/ja01332a063

upstream raw materials:

2,4-dibromophenol

benzyl chloride

benzyl bromide

4-benzyloxybenzyl alcohol

Downstream raw materials:

(E)-methyl 2-(2-(benzyloxy)-5-bromophenyl)-3-methoxyacrylate

2-(benzyloxy)-5-bromophenylboronic acid