Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate

Base Information

• Chemical Name: Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate
• CAS No.: 1150561-77-5
• Molecular Formula: C10H19BO4
• Molecular Weight: 214.069
• Hs Code.: 2931900090
• Mol file: 1150561-77-5.mol

Synonyms:Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate;2-(Methoxycarbonyl)ethylboronic acid, pinacol ester;Methyl 3-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)propanoate

Chemical Property of Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate

Chemical Property:

• Boiling Point: 242.7±23.0 °C(Predicted)
• PSA: 44.76000
• Density: 1.00±0.1 g/cm3(Predicted)
• LogP: 1.64170
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C

Purity/Quality:

98% ^*data from raw suppliers

2-(Methoxycarbonyl)ethylboronicacid,pinacolester ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate

There total 8 articles about Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + bis(pinacol)diborane (73183-34-3) → methyl 3-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate (1150561-77-5)

Guidance literature:

bis(pinacol)diborane; With copper(II) carbonate; triphenylphosphine; In water; at 20 ℃; for 0.5h; Inert atmosphere;

acrylic acid methyl ester; In water; at 27 ℃; for 10h; Inert atmosphere;

DOI:10.1002/aoc.2957

Reference yield: 92.0%

4,8-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,6,2-dioxazaborocane + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl 3-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate (1150561-77-5)

Guidance literature:

4,8-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,6,2-dioxazaborocane; With copper(l) chloride; In dichloromethane; for 0.166667h; Inert atmosphere;

acrylic acid methyl ester; In methanol; dichloromethane; at 0 - 20 ℃; for 15h; Inert atmosphere;

DOI:10.1021/ol901359n

Reference yield: 92.0%

4,8-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,6,2-dioxazaborocane + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl 3-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate (1150561-77-5)

Guidance literature:

With methanol; copper(l) chloride; In dichloromethane; at 0 - 20 ℃; chemoselective reaction; Inert atmosphere;

DOI:10.1021/jo2003488

upstream raw materials:

acrylic acid methyl ester

bis(pinacol)diborane

methanol

Methyl 3-bromopropionate

Downstream raw materials:

methyl 2-benzyl-3-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate

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