IDT‐nC6

Base Information

• Chemical Name: IDT‐nC6
• CAS No.: 1252555-61-5
• Molecular Formula: C70H90S2Sn2
• Molecular Weight: 1233.04
• Mol file: 1252555-61-5.mol

Synonyms:(4,4,9,9‐tetrakis(4‐ hexylphenyl)‐4,9‐dihydro‐sindaceno[ 1,2‐b:5,6‐ b']dithiophene‐2,7‐ diyl)bis(triMethylstannane);IDT‐nC6

Chemical Property of IDT‐nC6

Chemical Property:

• PSA: 56.48000
• LogP: 20.11740

Purity/Quality:

≥99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of IDT‐nC6

There total 3 articles about IDT‐nC6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

2,7-dibromo-4,4,9,9-tetrakis-(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b′]dithiophene (1049034-71-0) + trimethyltin(IV)chloride (1066-45-1) → 1,1'-[4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b’]dithiophene-2,7-diyl]bis[1,1,1-trimehtylstannyl] (1252555-61-5)

Guidance literature:

2,7-dibromo-4,4,9,9-tetrakis-(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b′]dithiophene; With n-butyllithium; In tetrahydrofuran; hexane; for 1.25h; Inert atmosphere;

trimethyltin(IV)chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1039/c3cc43229g

Reference yield: 82.0%

4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b’]dithiophene (1049034-67-4) + trimethyltin(IV)chloride (1066-45-1) → 1,1'-[4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b’]dithiophene-2,7-diyl]bis[1,1,1-trimehtylstannyl] (1252555-61-5)

Guidance literature:

4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b’]dithiophene; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 1h;

trimethyltin(IV)chloride; In tetrahydrofuran; hexane; at 20 ℃;

DOI:10.1039/c5ra23321f

Reference yield:

→ 1,1'-[4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b’]dithiophene-2,7-diyl]bis[1,1,1-trimehtylstannyl] (1252555-61-5)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

upstream raw materials:

2,7-dibromo-4,4,9,9-tetrakis-(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b′]dithiophene

trimethyltin(IV)chloride

4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b’]dithiophene

Downstream raw materials:

4,4'-(4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-sec-indaceno[1,2-b:5,6-b']dithiophene-2,7-diyl)bis(7-bromo-[1,2,5]thiadiazolo[3,4-c]pyridine)

C₁₂₄H₁₅₀N₄O₄S₆