Benzoylpyridinium-1-ylamine anion

Base Information

• Chemical Name: Benzoylpyridinium-1-ylamine anion
• CAS No.: 23031-08-5
• Molecular Formula: C₁₂H₁₀N₂O
• Molecular Weight: 198.224
• Mol file: 23031-08-5.mol

Synonyms:1-(Benzoylimino)pyridinium betaine inner salt (8ci);1-[(α-Oxylatobenzylidene)amino]pyridinium;Benzoylpyridinium-1-ylamine anion;N-Pyridiniobenzamide N-ide;Pyridine-1-benzenecarbonylimide

Chemical Property of Benzoylpyridinium-1-ylamine anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Benzoylpyridinium-1-ylamine anion

There total 13 articles about Benzoylpyridinium-1-ylamine anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

N-aminopyridin-1-ium iodide (6295-87-0) + benzoyl chloride (98-88-4) → benzoyl(pyridin-1-ium-1-yl)amide (23031-08-5)

Guidance literature:

N-aminopyridin-1-ium iodide; With sodium hydroxide; In water; at 0 ℃; for 0.166667h;

benzoyl chloride; In water; at 0 - 20 ℃;

DOI:10.1039/c3cc45410j

Reference yield: 41.0%

pyridine (110-86-1) + benzoyl azide (582-61-6) → benzoyl(pyridin-1-ium-1-yl)amide (23031-08-5)

Guidance literature:

for 18.5h; UV-irradiation; cooling;

DOI:10.1071/CH07027

Reference yield:

pyridine (110-86-1) + benzoyl chloride (98-88-4) → benzoyl(pyridin-1-ium-1-yl)amide (23031-08-5)

Guidance literature:

pyridine; With O-(2,4-dinitrophenyl)hydroxylamine; In tetrahydrofuran; water; at 40 ℃; for 16h;

With sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 0.0833333h;

benzoyl chloride; In tetrahydrofuran; water; at 20 ℃; for 5h;

DOI:10.1021/jo4002883

upstream raw materials:

benzoyl chloride

1-propylideneaminopyridinium bromide

pyridine

benzoyl azide

Downstream raw materials:

1,3-Bis-[2,3-bis-(4-tert-butyl-phenylsulfanyl)-cycloprop-2-enylidene]-urea

2,4,5-triphenyl-1,3-oxazin-6-one

C₁₉H₁₈N₂O₃

2-(E)-(4-(trifluoromethyl)styryl)-N-benzoyliminopyridinium ylide

Refernces

• 1、 Moon, Yonghoon,Lee, Wooseok,Hong, Sungwoo. "Visible-Light-Enabled Ortho-Selective Aminopyridylation of Alkenes with N-Aminopyridinium Ylides". supporting information. p. 12420 - 12429. Retrieved 2020/07/24.
• 2、 Fang, Lei,Chen, Liangshun,Yu, Jianjun,Wang, Limin. "Benzoyl peroxide promoted radical ortho-alkylation of nitrogen heteroaromatics with simple alkanes and alcohols". supporting information. p. 1910 - 1914. Retrieved 2015/03/18.