(E)-N,N,N',N'-Tetraethyl-2-butene-1,4-diamine

Base Information

• Chemical Name: (E)-N,N,N',N'-Tetraethyl-2-butene-1,4-diamine
• CAS No.: 20412-52-6
• Molecular Formula: C₁₂H₂₆N₂
• Molecular Weight: 198.352
• European Community (EC) Number: 203-276-2,635-766-0
• NSC Number: 75614
• DSSTox Substance ID: DTXSID20883296
• Nikkaji Number: J182.193H,J42.741A
• Wikidata: Q82862371
• Mol file: 20412-52-6.mol

Synonyms:E-TED diamine;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene dibenzoate, (E)-isomer;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene dihydrobromide, (E)-isomer;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene fumarate, (E)-isomer;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene phosphate, (E)-isomer;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene, (E)-isomer;N,N,N',N'-tetraethyl-1,4-diaminobut-2-ene, (Z)-isomer

Chemical Property of (E)-N,N,N',N'-Tetraethyl-2-butene-1,4-diamine

Chemical Property:

• Boiling Point: 254.7°Cat760mmHg
• Flash Point: 97.6°C
• PSA: 6.48000
• Density: 0.844g/cm³
• LogP: 2.22620
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 198.209598838
• Heavy Atom Count: 14
• Complexity: 119

Purity/Quality:

99% ^*data from raw suppliers

N,N,N',N'-TETRAETHYL-2-BUTENE-1,4-DIAMINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN(CC)CC=CCN(CC)CC
• Isomeric SMILES: CCN(CC)C/C=C/CN(CC)CC

Technology Process of (E)-N,N,N',N'-Tetraethyl-2-butene-1,4-diamine

There total 5 articles about (E)-N,N,N',N'-Tetraethyl-2-butene-1,4-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(E)-1,4-dibromobutene (821-06-7) + diethylamine (109-89-7) → trans-N,N,N',N'-tetraethyl-2-butene-1,4-diamine (105-17-9,20412-52-6)

Guidance literature:

In benzene; at 0 ℃;

DOI:10.1002/ps.2780410112

Reference yield: 66.09%

trans-1,4-dichlorobut-2-ene (110-57-6) + diethylamine (109-89-7) → trans-N,N,N',N'-tetraethyl-2-butene-1,4-diamine (105-17-9,20412-52-6)

Guidance literature:

at 50 - 70 ℃;

Reference yield: 8.0%

N,N,N',N'-Tetraethyl-1,4-diaminobut-2-yne (105-18-0) → (Z)-N,N,N',N'-Tetraethyl-1,4-diaminobut-2-ene (20412-52-6)

Guidance literature:

With copper(I) bromide; lithium bromide; In tetrahydrofuran; for 4h; Heating;

DOI:10.1002/ps.2780410112

upstream raw materials:

trans-1,4-dichlorobut-2-ene

diethylamine

(E)-1,4-dibromobutene

N,N,N',N'-Tetraethyl-1,4-diaminobut-2-yne