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trans-1,4-Dichloro-2-butene CAS 110-57-6 (E)-1,4-Dichloro-2-butene IN Stock Dichloro(trans-1,4-)-2-Butene CAS 110-57-6
Cas No: 110-57-6
USD $ 3.5-5.0 / Kiloliter 5 Kiloliter 3000 Metric Ton/Month Chemwill Asia Co., Ltd. Contact Supplier
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trans-1,4-Dichloro-2-butene110-57-6
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Amadis Chemical offer CAS#110-57-6;CAT#A802220
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trans-1,4-Dichloro-2-butene
Cas No: 110-57-6
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TIANFUCHEM--110-57-6--trans-1,4-Dichloro-2-butene factory price
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Pharmaceutical Grade CAS 110-57-6 with competitive price
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trans-1,4-Dichloro-2-butene 110-57-6
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99% Purity.CAS110-57-6
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trans-1,4-Dichloro-2-butene CAS NO.110-57-6
Cas No: 110-57-6
USD $ 1.0-2.0 / Gram 10 Gram 100 Metric Ton/Day Jilin Tely Imp.& Exp.Co., Ltd. Contact Supplier

110-57-6 Usage

General Description

Colorless liquid with a distinct odor. An intermediate for hexamethylenediamine and chloroprene.

Reactivity Profile

trans-1,4-Dichloro-2-butene will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. [EPA, 1998].

Health Hazard

(Non-Specific -- Dichlorobutene) Liquid and vapors from the material are highly corrosive and may damage skin, eyes, lungs, and internal organs.

Air & Water Reactions

Insoluble in water.

Fire Hazard

The material will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds.

Chemical Properties

clear colorless to light yellow liquid
InChI:InChI=1/C4H6Cl2/c5-3-1-2-4-6/h1,3H,2,4H2

110-57-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name trans-1,4-Dichloro-2-butene

1.2 Other means of identification

Product number -
Other names trans 1,4-dichloro-2-butene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-57-6 SDS

110-57-6Synthetic route

3,4-dichlorobut-1-ene
310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

Conditions
ConditionsYield
With poly(tetrafluoroethylene); iron oxide nanoparticles; oxygen at 100℃; for 0.5h;67%
With copper(l) chloride at 175℃;
With aluminium trichloride; iron(III) chloride at -10 - -5℃;
buta-1,3-diene
106-99-0

buta-1,3-diene

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

Conditions
ConditionsYield
With tetrachloromethane; chlorine at -80℃; unter Lichtausschluss;
With pyridine; tetrachloromethane; chlorine at -80℃; unter Lichtausschluss;
buta-1,3-diene
106-99-0

buta-1,3-diene

A

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

B

3,4-dichlorobut-1-ene
310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

Conditions
ConditionsYield
With chlorine at 60 - 75℃; in der Dampfphase;
With chlorine at 60 - 75℃; in verschiedenen Loesungsmitteln unter Kuehlung;
at 25℃; electrolysis; anolyte=CoCl2-MeCN, catholyte=NH4Cl-H2O;
buta-1,3-diene
106-99-0

buta-1,3-diene

A

Z-1,4-dichlorobutene
1476-11-5

Z-1,4-dichlorobutene

B

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

C

3,4-dichlorobut-1-ene
310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

Conditions
ConditionsYield
With iodine; copper dichloride In benzene at 70℃; for 2h;
With copper dichloride In acetonitrile at 60℃; for 2h;
1,4-dichloro-2-butene
764-41-0

1,4-dichloro-2-butene

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

methanol
67-56-1

methanol

buta-1,3-diene
106-99-0

buta-1,3-diene

A

4-Chlor-3-methoxy-but-1-en
7795-90-6

4-Chlor-3-methoxy-but-1-en

B

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

C

3,4-dichlorobut-1-ene
310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

D

1-chloro-4-methoxy-2-butene
57513-14-1

1-chloro-4-methoxy-2-butene

Conditions
ConditionsYield
With tert-butylhypochlorite at 0 - 5℃; Further byproducts given;
With tert-butylhypochlorite at -5 - 0℃; Further byproducts given. Title compound not separated from byproducts;
trans-1-bromo-4-chloro-2-butene
102776-00-1

trans-1-bromo-4-chloro-2-butene

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

Conditions
ConditionsYield
With (C4H9)N(1+)*Cl(1-) In dichloromethane at 0℃; for 24h; Title compound not separated from byproducts;95 % Chromat.
3,4-dichlorobut-1-ene
310447-99-5, 310448-01-2

3,4-dichlorobut-1-ene

A

Z-1,4-dichlorobutene
1476-11-5

Z-1,4-dichlorobutene

B

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

Conditions
ConditionsYield
With poly(p-xylylene); palladium In toluene at 99.85℃; Product distribution;
With oxygen at 100℃;
Z-1,4-dichlorobutene
1476-11-5

Z-1,4-dichlorobutene

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

Conditions
ConditionsYield
With maleic anhydride In acetone for 4h; Irradiation; Inert atmosphere;
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

tributylphosphine
998-40-3

tributylphosphine

(E)-but-2-ene-1,4-diylbis(tributylphosphonium) dichloride
36288-32-1, 134839-26-2

(E)-but-2-ene-1,4-diylbis(tributylphosphonium) dichloride

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene at 20℃; for 18h; Inert atmosphere; Reflux;100%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

iminodicarboxylic acid di-tert-butyl ester
51779-32-9

iminodicarboxylic acid di-tert-butyl ester

C14H24ClNO4
121030-31-7

C14H24ClNO4

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 60℃; for 3h;98%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

triethyl phosphite
122-52-1

triethyl phosphite

tetraethyl (E)-2-butene-1,4-diphosphonate
1112-96-5, 16626-80-5, 56727-14-1

tetraethyl (E)-2-butene-1,4-diphosphonate

Conditions
ConditionsYield
at 150 - 193℃; for 1h; Arbuzov reaction;97%
at 140℃; for 12h; Inert atmosphere;97%
at 134 - 144℃; for 33.5h;94.1%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

trimethylamine
75-50-3

trimethylamine

trans-1-chloro-4-methylammonio-2-butene chloride
60347-24-2

trans-1-chloro-4-methylammonio-2-butene chloride

Conditions
ConditionsYield
In tetrahydrofuran for 6h; Ambient temperature;95%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

triethyl phosphite
122-52-1

triethyl phosphite

tetraethyl trans-2-butenyl-1,4-bisphosphonate
211677-08-6

tetraethyl trans-2-butenyl-1,4-bisphosphonate

Conditions
ConditionsYield
at 133 - 144℃; for 2.16667h; Inert atmosphere;94.1%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

anthracene
120-12-7

anthracene

11,12-bis(chloromethyl)-9,10-dihydro-9,10-ethanoanthracene

11,12-bis(chloromethyl)-9,10-dihydro-9,10-ethanoanthracene

Conditions
ConditionsYield
at 200℃; for 48h; Sealed tube;91%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

1,4-dichloro-2,3-butanediol
2419-73-0

1,4-dichloro-2,3-butanediol

Conditions
ConditionsYield
With tetraethylammonium acetate; 4-methylmorpholine N-oxide; Mg(1-x)Al(x)(OH)2(Cl)2*zH2O-OsO4 In water; acetone; acetonitrile at 20℃;90%
With potassium permanganate; magnesium sulfate at -15℃;
With potassium permanganate; acetone at -35℃;
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

2-[5-(tetrahydropyran-2-yloxy)pent-3-ynyl]malonic acid dimethyl ester
111036-27-2

2-[5-(tetrahydropyran-2-yloxy)pent-3-ynyl]malonic acid dimethyl ester

methyl 2-carbomethoxy-2-<(E)-4-chloro-2-butenyl>-7-<(tetrahydro-2H-pyran-2-yl)oxy>-5-heptynoate
111014-17-6

methyl 2-carbomethoxy-2-<(E)-4-chloro-2-butenyl>-7-<(tetrahydro-2H-pyran-2-yl)oxy>-5-heptynoate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran 1.) reflux, 30 min; 2.) 25 deg C, then reflux, 30 min;90%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

N-(tert-butyloxycarbonyl)(2,4,6-triisopropylphenyl)sulfonamide
335004-12-1

N-(tert-butyloxycarbonyl)(2,4,6-triisopropylphenyl)sulfonamide

N-[(E)-4-chloro-2-buten-1-yl]-N-(tert-butoxycarbonyl)-(2,4,6-triisopropyl)phenylsulfonamide
918401-82-8

N-[(E)-4-chloro-2-buten-1-yl]-N-(tert-butoxycarbonyl)-(2,4,6-triisopropyl)phenylsulfonamide

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 16h; Heating;90%
1,3-dihydro-3,3,7-trimethyl-2H-indol-2-one
19501-89-4

1,3-dihydro-3,3,7-trimethyl-2H-indol-2-one

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

4-(1-(trans-4-chloro-2-butenyl)oxy)-2,3-dihydro-3,3,7-trimethyl-1H-indol-2-one
170683-22-4

4-(1-(trans-4-chloro-2-butenyl)oxy)-2,3-dihydro-3,3,7-trimethyl-1H-indol-2-one

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran; hexane; water; N,N-dimethyl-formamide90%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

Methyl phenyl sulfone
3112-85-4

Methyl phenyl sulfone

(E)-1-chloro-5-(phenylsulfonyl)pent-2-ene
1187312-40-8

(E)-1-chloro-5-(phenylsulfonyl)pent-2-ene

Conditions
ConditionsYield
Stage #1: methylphenylsulfonate With n-butyllithium In tetrahydrofuran; hexane at -40℃; for 0.0833333h;
Stage #2: With copper(l) iodide In tetrahydrofuran; hexane; N,N-dimethyl-formamide at -40 - 0℃; for 1h;
Stage #3: trans-1,4-dichlorobut-2-ene In tetrahydrofuran; hexane; N,N-dimethyl-formamide at 0℃; for 1h;
90%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

phenylacetylene
536-74-3

phenylacetylene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

(S,E)-2-(3-(chloromethyl)-2-phenylpenta-1,4-dien-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(S,E)-2-(3-(chloromethyl)-2-phenylpenta-1,4-dien-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
Stage #1: bis(pinacol)diborane With (C6H5)2C3N2H3((CH3)3C6H2)C6H4SO3; copper(l) chloride; sodium t-butanolate In toluene Inert atmosphere; Schlenk technique;
Stage #2: trans-1,4-dichlorobut-2-ene; phenylacetylene In toluene at 30℃; for 16h; Inert atmosphere; Schlenk technique; enantioselective reaction;
90%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

11-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-butadiene

11-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-butadiene

Conditions
ConditionsYield
Stage #1: trans-1,4-dichlorobut-2-ene With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran at -90℃; for 0.25h;
Stage #2: bis(pinacol)diborane In tetrahydrofuran at -90 - 20℃;
89%
Stage #1: trans-1,4-dichlorobut-2-ene With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran at -90℃;
Stage #2: bis(pinacol)diborane In tetrahydrofuran at -90 - 20℃;
89%
With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran at -90°C, 15 min;89%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

(3aR,4S,7R,7aS)‑4,7‑methylene‑1H‑isoindole‑1,3(2H)-dione
14805-29-9

(3aR,4S,7R,7aS)‑4,7‑methylene‑1H‑isoindole‑1,3(2H)-dione

N-(4-Chloro-2-trans-butenyl)bicyclo<2.2.1>heptane-2,3-di-exo-carboximide
105981-25-7

N-(4-Chloro-2-trans-butenyl)bicyclo<2.2.1>heptane-2,3-di-exo-carboximide

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 90 - 100℃; for 2h;88.7%
N,N'-dimethylbenzylamine
103-83-3

N,N'-dimethylbenzylamine

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

C22H32N2(2+)*2Cl(1-)
100186-77-4

C22H32N2(2+)*2Cl(1-)

Conditions
ConditionsYield
In acetonitrile for 0.5h; Ambient temperature; Heating;87%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

1-chloro-1,3-bis(2,4,6-trichlorophenyl)triazene
187464-05-7

1-chloro-1,3-bis(2,4,6-trichlorophenyl)triazene

A

(Z)-4,5-bis(chloromethyl)-1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

(Z)-4,5-bis(chloromethyl)-1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

(E)-4,5-bis(chloromethyl)-1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

(E)-4,5-bis(chloromethyl)-1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

Conditions
ConditionsYield
With antimonypentachloride In dichloromethane at -60 - 23℃; for 1.75h;A 14 % Spectr.
B 87%
With antimonypentachloride In dichloromethane at -60 - 23℃; for 1.75h;A 14 % Spectr.
B 80%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

salicylaldehyde
90-02-8

salicylaldehyde

2,2'-[but-2-ene-1,4-diylbis(oxy)]dibenzaldehyde
918655-71-7

2,2'-[but-2-ene-1,4-diylbis(oxy)]dibenzaldehyde

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide for 0.25h; Heating;87%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

A

(1Z)-1-chloro-1,3-butadiene
10033-99-5

(1Z)-1-chloro-1,3-butadiene

B

1-chloro-1E,3-butadiene
16503-25-6

1-chloro-1E,3-butadiene

Conditions
ConditionsYield
With sodium hydroxide; Aliquat 336 In water at 50 - 60℃; under 10 Torr; Dehydrochlorination; Title compound not separated from byproducts;A 86%
B n/a
With potassium hydroxide In various solvent(s) at 85℃; Title compound not separated from byproducts.;
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

dimethyl 2-vinylcyclopropane-1,1-dicarboxylate
17447-60-8

dimethyl 2-vinylcyclopropane-1,1-dicarboxylate

Conditions
ConditionsYield
With sodium methylate In methanol 1.) RT, 45 min; 2.) 50 deg C, 3 h;85%
With methanol; sodium In methanol at 55℃; for 3h;58%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

4-bromo-4'-hydroxybiphenyl
29558-77-8

4-bromo-4'-hydroxybiphenyl

(E)-4-(4'-Bromo-biphenyl-4-yloxy)-but-2-en-1-ol

(E)-4-(4'-Bromo-biphenyl-4-yloxy)-but-2-en-1-ol

Conditions
ConditionsYield
Stage #1: trans-1,4-dichlorobut-2-ene; 4-bromo-4'-hydroxybiphenyl With potassium carbonate at 20℃; for 96h;
Stage #2: With tetrabutylammonium acetate In acetone Heating;
Stage #3: With methanol; sodium hydroxide at 20℃; for 12h;
85%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

N-(tert-butyloxycarbonyl)-4-fluorobenzenesulfonamide
501682-72-0

N-(tert-butyloxycarbonyl)-4-fluorobenzenesulfonamide

N-[(E)-4-chloro-2-buten-1-yl]-N-(tert-butoxycarbonyl)-(4-fluorophenyl)sulfonamide
918401-81-7

N-[(E)-4-chloro-2-buten-1-yl]-N-(tert-butoxycarbonyl)-(4-fluorophenyl)sulfonamide

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 16h; Heating;85%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

methyl 2-carbomethoxy-10-<(tetrahydro-2H-pyran-2-yl)oxy>-8-decynoate
114952-70-4

methyl 2-carbomethoxy-10-<(tetrahydro-2H-pyran-2-yl)oxy>-8-decynoate

2-((E)-4-Chloro-but-2-enyl)-2-[8-(tetrahydro-pyran-2-yloxy)-oct-6-ynyl]-malonic acid dimethyl ester
114939-17-2

2-((E)-4-Chloro-but-2-enyl)-2-[8-(tetrahydro-pyran-2-yloxy)-oct-6-ynyl]-malonic acid dimethyl ester

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 0.666667h; Heating;84%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

methyl (E)-2-carbomethoxy-7-<(tetrahydro-2H-pyran-2-yl)oxy>-5-heptenoate
111013-96-8

methyl (E)-2-carbomethoxy-7-<(tetrahydro-2H-pyran-2-yl)oxy>-5-heptenoate

methyl (E)-2-carbomethoxy-2-<(E)-4-chloro-2-butenyl>-7-<(tetrahydro-2H-pyran-2-yl)oxy>-5-heptenoate
111014-08-5

methyl (E)-2-carbomethoxy-2-<(E)-4-chloro-2-butenyl>-7-<(tetrahydro-2H-pyran-2-yl)oxy>-5-heptenoate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran 1.) reflux, 30 min; 2.) 25 deg C, then reflux, 30 min;84%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

(2R,3R)-1,4-dichloro-2,3-dihydroxybutane
221467-90-9

(2R,3R)-1,4-dichloro-2,3-dihydroxybutane

Conditions
ConditionsYield
With Hydroquinone 1,4-phthalazinediyl diether; potassium dioxotetrahydroxoosmate(VI); methanesulfonamide; sodium hydrogencarbonate; potassium carbonate; potassium hexacyanoferrate(III) In water; tert-butyl alcohol at 0℃;84%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

2-((Z)-6-Chloro-3-methyl-5-triisopropylsilanyloxy-hex-3-enyl)-malonic acid dimethyl ester
244262-62-2

2-((Z)-6-Chloro-3-methyl-5-triisopropylsilanyloxy-hex-3-enyl)-malonic acid dimethyl ester

2-((E)-4-Chloro-but-2-enyl)-2-((Z)-6-chloro-3-methyl-5-triisopropylsilanyloxy-hex-3-enyl)-malonic acid dimethyl ester
244262-65-5

2-((E)-4-Chloro-but-2-enyl)-2-((Z)-6-chloro-3-methyl-5-triisopropylsilanyloxy-hex-3-enyl)-malonic acid dimethyl ester

Conditions
ConditionsYield
Stage #1: 2-((Z)-6-Chloro-3-methyl-5-triisopropylsilanyloxy-hex-3-enyl)-malonic acid dimethyl ester With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide at 20℃; Metallation;
Stage #2: trans-1,4-dichlorobut-2-ene In tetrahydrofuran; N,N-dimethyl-formamide at 75℃; Alkylation;
83%
1,4-diaza-bicyclo[2.2.2]octane
280-57-9

1,4-diaza-bicyclo[2.2.2]octane

trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

(E)-1,4-Bis-(1'-azonia-4'-azobicyclo[2.2.2]octyl)but-2-ene dichloride

(E)-1,4-Bis-(1'-azonia-4'-azobicyclo[2.2.2]octyl)but-2-ene dichloride

Conditions
ConditionsYield
In acetonitrile for 24h; Alkylation; Heating;82%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

3-tert-butyl-2-cyclopenten-1-one
5682-70-2

3-tert-butyl-2-cyclopenten-1-one

5-tert-butyl-6,7-bis(chloromethyl)bicyclo[3.2.0]heptan-2-one
767565-08-2

5-tert-butyl-6,7-bis(chloromethyl)bicyclo[3.2.0]heptan-2-one

Conditions
ConditionsYield
In dichloromethane at 12℃; for 10h; Irradiation;82%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

methyl (Z)-2-carbomethoxy-8-<(tetrahydro-2H-pyran-2-yl)oxy>-6-octenoate
111013-93-5

methyl (Z)-2-carbomethoxy-8-<(tetrahydro-2H-pyran-2-yl)oxy>-6-octenoate

methyl (Z)-2-carbomethoxy-2-<(E)-4-chloro-2-butenyl>-8-<(tetrahydro-2H-pyran-2-yl)oxy>-6-octenoate
111014-32-5

methyl (Z)-2-carbomethoxy-2-<(E)-4-chloro-2-butenyl>-8-<(tetrahydro-2H-pyran-2-yl)oxy>-6-octenoate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran 1.) reflux, 30 min; 2.) 25 deg C, then reflux, 30 min;81%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

N-(4-(3-chloro-4-fluorophenyl))-7-(2-(3-methyl-3-aza-bicyclo[3.1.0]-6-hexyl)-ethoxy)quinazolin-4,6-diamine
1363359-89-0

N-(4-(3-chloro-4-fluorophenyl))-7-(2-(3-methyl-3-aza-bicyclo[3.1.0]-6-hexyl)-ethoxy)quinazolin-4,6-diamine

(E)-N-[4-(3-chloro-4-fluorophenylamino)-7-((2-(3-methyl-3-aza-bicyclo[3.1.0]-6-hexyl)-ethoxy)-quinazolin-6-yl-4-chloro)]-crotonamide
1363569-81-6

(E)-N-[4-(3-chloro-4-fluorophenylamino)-7-((2-(3-methyl-3-aza-bicyclo[3.1.0]-6-hexyl)-ethoxy)-quinazolin-6-yl-4-chloro)]-crotonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 0.5h; Cooling with ice;81%
trans-1,4-dichlorobut-2-ene
110-57-6

trans-1,4-dichlorobut-2-ene

2-[(E)-4-(Tetrahydro-pyran-2-yloxy)-but-2-enyl]-malonic acid dimethyl ester
93915-02-7

2-[(E)-4-(Tetrahydro-pyran-2-yloxy)-but-2-enyl]-malonic acid dimethyl ester

2-((E)-4-Chloro-but-2-enyl)-2-[(E)-4-(tetrahydro-pyran-2-yloxy)-but-2-enyl]-malonic acid dimethyl ester
112181-18-7

2-((E)-4-Chloro-but-2-enyl)-2-[(E)-4-(tetrahydro-pyran-2-yloxy)-but-2-enyl]-malonic acid dimethyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 90℃; for 12h; Inert atmosphere;80%
With potassium carbonate In tetrahydrofuran; N,N-dimethyl-formamide for 13h; Heating;45%

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