[N-(2-(Trimethylsilyl)ethanesulfonyl)imino]phenyliodane

Base Information

• Chemical Name: [N-(2-(Trimethylsilyl)ethanesulfonyl)imino]phenyliodane
• CAS No.: 236122-13-7
• Molecular Formula: C11H18INO2SSi
• Molecular Weight: 383.325
• Mol file: 236122-13-7.mol

Synonyms:[N-(2-(Trimethylsilyl)ethanesulfonyl)imino]phenyliodane

Chemical Property of [N-(2-(Trimethylsilyl)ethanesulfonyl)imino]phenyliodane

Chemical Property:

• PSA: 54.88000
• LogP: 4.75930

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Physical properties: mp 84–85.5 °C.
• Uses: [N-(2-(Trimethylsilyl)ethanesulfonyl)- imino]phenyliodane is a iodine(III) reagent used as a nitrogen atom source in the transition-metal catalyzed aziridination of olefins or in the sulfoximination of sulfoxides. It participates in the reactions of Copper-Catalyzed Aziridination of Olefins, Sulfoximination of Sulfoxides, etc.

Technology Process of [N-(2-(Trimethylsilyl)ethanesulfonyl)imino]phenyliodane

There total 1 articles about [N-(2-(Trimethylsilyl)ethanesulfonyl)imino]phenyliodane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + 2-(trimethylsilyl)ethanesulfonamide (125486-96-6) → 2-(trimethylsilyl)-N-(phenyl-λ3-iodanylidene)-ethanesulfonamide (236122-13-7)

Guidance literature:

With potassium hydroxide; In methanol; 1.) 0 deg C, 30 min, 2.) 20 deg C, 3 h;

DOI:10.1021/jo990356x

Reference yield: 96.0%

1-methoxy-4-(methylsulfinyl)benzene (3517-99-5) + 2-(trimethylsilyl)-N-(phenyl-λ3-iodanylidene)-ethanesulfonamide (236122-13-7) → S-methyl-S-(4-methoxyphenyl)-N-[[2-(trimethylsilyl)ethyl]sulfonyl]sulfoximine (1027729-47-0)

Guidance literature:

tetrakis(acetonitrile)copper(I) hexafluorophosphate; In acetonitrile; at 0 - 20 ℃; for 20h;

Reference yield: 74.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-(trimethylsilyl)-N-(phenyl-λ3-iodanylidene)-ethanesulfonamide (236122-13-7) → N-[2-(trimethylsilyl)ethanesulfonyl]-2-phenylaziridine (236122-14-8)

Guidance literature:

With iron(II) triflate; In acetonitrile; at 20 ℃; Molecular sieve;

DOI:10.1002/adsc.200700519

upstream raw materials:

[bis(acetoxy)iodo]benzene

2-(trimethylsilyl)ethanesulfonamide

Downstream raw materials:

N-[2-(trimethylsilyl)ethanesulfonyl]-2-phenylaziridine

N-(2-(trimethylsilyl)ethanesulfonyl)-2-(2-phenylethyl)aziridine

N-(2-(trimethylsilyl)ethanesulfonyl)-2-(methoxycarbonyl)-3-phenylaziridine

N-(2-trimethylsilylethylsulfonyl)-S-methyl-S-phenylsulfoximine

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