(Diacetoxyiodo)benzene

Base Information Edit

Chemical Name:(Diacetoxyiodo)benzene
CAS No.:3240-34-4
Deprecated CAS:76546-99-1,94569-95-6,207518-80-7,359635-52-2,864365-82-2,864365-83-3,1071215-62-7,1257985-44-6,1313808-31-9,1313808-32-0,1330185-09-5,1071215-62-7,1257985-44-6,207518-80-7,359635-52-2,864365-82-2,864365-83-3
Molecular Formula:C10H11IO4
Molecular Weight:322.099
Hs Code.:29310095
European Community (EC) Number:221-808-1
NSC Number:226375,23801
DSSTox Substance ID:DTXSID0062929
Nikkaji Number:J54.893F
Wikipedia:(Diacetoxyiodo)benzene
Wikidata:Q3025837
ChEMBL ID:CHEMBL3391738
Mol file:3240-34-4.mol

Synonyms:(Diacetoxyiodo)benzene;Iodosobenzene diacetate;PIA;

Suppliers and Price of (Diacetoxyiodo)benzene

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(Diacetoxyiodo)benzene
500g
$ 210.00

TRC
(Diacetoxyiodo)benzene
50g
$ 60.00

TCI Chemical
Iodobenzene Diacetate >97.0%(T)
10g
$ 24.00

TCI Chemical
Iodobenzene Diacetate >97.0%(T)
25g
$ 47.00

TCI Chemical
Iodobenzene Diacetate >97.0%(T)
250g
$ 299.00

Sigma-Aldrich
(Diacetoxyiodo)benzene 98%
100g
$ 218.00

Sigma-Aldrich
(Diacetoxyiodo)benzene 98%
25g
$ 57.30

Sigma-Aldrich
(Diacetoxyiodo)benzene 98%
5g
$ 19.10

Oakwood
(Diacetoxyiodo)benzene 98%
25g
$ 20.00

Oakwood
(Diacetoxyiodo)benzene 98%
1g
$ 10.00

Total 211 raw suppliers

Chemical Property of (Diacetoxyiodo)benzene Edit

Chemical Property:

Appearance/Colour:white to light yellow crystal powder
Vapor Pressure:3.87E-09mmHg at 25°C
Melting Point:161-163 °C(lit.)
Refractive Index:n/D 1.444
Boiling Point:456.8ºC at 760 mmHg
Flash Point:230.1ºC
PSA：52.60000
Density:1.6865 (estimate)
LogP:2.31880
Storage Temp.:-20°C
Sensitive.:Light Sensitive
Solubility.:INSOLUBLE
Water Solubility.:INSOLUBLE
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:321.97021
Heavy Atom Count:15
Complexity:220

Purity/Quality:

99% ^*data from raw suppliers

(Diacetoxyiodo)benzene ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 22-24/25-37/39-26-36/37/39-27

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Other Classes -> Halogenated Monoaromatics
Canonical SMILES:CC(=O)OI(C1=CC=CC=C1)OC(=O)C
Uses (Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic a cid into the corresponding aldehydes, ketones and nitriles. (Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic acid into the corresponding aldehydes, ketones and nitriles.

Technology Process of (Diacetoxyiodo)benzene

There total 16 articles about (Diacetoxyiodo)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%