Diethyl-d10 Chlorothiophosphate

Base Information

• Chemical Name: Diethyl-d10 Chlorothiophosphate
• CAS No.: 287397-89-1
• Molecular Formula: C4ClD10O2PS
• Molecular Weight: 198.67437878
• Mol file: 287397-89-1.mol

Synonyms:Diethyl-d10 Chlorothiophosphate;Diethyl Chlorothiophosphate-d10;NSC 43776-d10;O,O-(Diethyl-d10) Thiophosphoryl Chloride;Phosphorochloridothioic Acid O,O-(Diethyl-d10) Ester

Chemical Property of Diethyl-d10 Chlorothiophosphate

Chemical Property:

• Vapor Pressure: 0.866mmHg at 25°C
• Boiling Point: 187.489°C at 760 mmHg
• Flash Point: 75.824°C
• PSA: 60.36000
• Density: 1.318g/cm³
• LogP: 3.17330

Purity/Quality:

97% ^*data from raw suppliers

Diethyl Chlorothiophosphate-d10 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diethyl-d10 Chlorothiophosphate

There total 1 articles about Diethyl-d10 Chlorothiophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyldithiophosphoric acid-d10 → diethyl chlorothiophosphate-d10 (287397-89-1)

Guidance literature:

With chlorine; In benzene; at 15 ℃; for 0.333333h;

DOI:10.1021/jf991125u

Reference yield: 93.8%

3-chloro-4-methylumbelliferone (6174-86-3) + diethyl chlorothiophosphate-d10 (287397-89-1) → coumaphos-d10 (287397-86-8)

Guidance literature:

With potassium carbonate; In acetone; for 4h; Heating;

DOI:10.1021/jf991125u

Reference yield:

3,5,6-trichloropyridin-2 ol (6515-38-4) + diethyl chlorothiophosphate-d10 (287397-89-1) → chlorpyrifos-D10 (285138-81-0)

Guidance literature:

With dmap; N-benzyl-N,N,N-triethylammonium chloride; boric acid; sodium chloride; sodium hydroxide; In dichloromethane; water; at 40 - 50 ℃;

Downstream raw materials:

coumaphos-d10

chlorpyrifos-D10

Refernces

• 1、 Kochansky, Jan. "Synthesis of (diethyl-d10) coumaphos and related compounds". . p. 2826 - 2828. Retrieved 2007/10/03.