2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester

Base Information

Chemical Name:2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester
CAS No.:41641-27-4
Molecular Formula:C12H20O2
Molecular Weight:196.29
Hs Code.:
DSSTox Substance ID:DTXSID301140773
Nikkaji Number:J441.668F
Mol file:41641-27-4.mol

Synonyms:SCHEMBL6054986;DTXSID301140773;41641-27-4;2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester;Ethyl (1S,3S)-2,2-dimethyl-3-(2-methyl-1-propen-1-yl)cyclopropanecarboxylate

Suppliers and Price of 2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester

Chemical Property:

Boiling Point:60 °C (0.5 mmHg)
PSA：26.30000
LogP:2.78790
XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:196.146329876
Heavy Atom Count:14
Complexity:260

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1C(C1(C)C)C=C(C)C
Isomeric SMILES:CCOC(=O)[C@H]1[C@@H](C1(C)C)C=C(C)C

Technology Process of 2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester

There total 46 articles about 2,2-Dimethyl-3beta-(2-methyl-1-propenyl)cyclopropane-1alpha-carboxylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 97-41-6
ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate

: 97-41-6,1802-02-4,7377-84-6,15543-65-4,16642-27-6,34909-55-2,41641-25-2,41641-26-3,41641-27-4
ethyl trans-(+/-)-chrysanthemate

Guidance literature:: With sodium hydride; In mineral oil; for 3h; Inert atmosphere;
DOI:10.1021/acs.joc.9b02767

Reference yield: 92.63%

: 764-13-6
2,5-Dimethyl-2,4-hexadiene

: 20739-39-3
1-acetoxy-2-aminoethane hydrochloride

: 97-41-6,1802-02-4,7377-84-6,15543-65-4,16642-27-6,34909-55-2,41641-25-2,41641-26-3,41641-27-4
ethyl trans-(+/-)-chrysanthemate

Guidance literature:: 1-acetoxy-2-aminoethane hydrochloride; With sodium nitrite; In water; 1,2-dichloro-ethane; at -2 - 2 ℃;

2,5-Dimethyl-2,4-hexadiene; With 2,6-di-tert-butyl-4-methyl-phenol; copper(l) chloride; In 1,2-dichloro-ethane; at 55 - 60 ℃;

Reference yield: 80.0%

: 623-73-4
diazoacetic acid ethyl ester

: 764-13-6
2,5-Dimethyl-2,4-hexadiene

: 97-41-6
ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate

: 41641-25-2
ethyl 2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarboxylate

: 41641-27-4
ethyl 2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarboxylate

Guidance literature:: 2,5-Dimethyl-2,4-hexadiene; With C₃₀H₂₇FeN₂P; 2Cu⁽¹⁺⁾*2CF₃O₃S^(1-)*0.5C₆H₆; In 1,2-dichloro-ethane; at 60 ℃; for 0.5h; Inert atmosphere; Molecular sieve; Industrial scale;

diazoacetic acid ethyl ester; In 1,2-dichloro-ethane; for 18h; Reagent/catalyst; enantioselective reaction; Inert atmosphere; Molecular sieve; Industrial scale;