Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate)

Base Information

Chemical Name:Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate)
CAS No.:107952-66-9
Molecular Formula:C₁₄H₂₀O₁₀
Molecular Weight:348.307
Hs Code.:
Mol file:107952-66-9.mol

Synonyms:Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate)

Suppliers and Price of Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl3,4-Di-O-acetyl-β-L-idopyranosiduronate1,2-(Methylorthoacetate)
10mg
$ 120.00

American Custom Chemicals Corporation
METHYL-3,4-DI-O-ACETYL-BETA-L-IDOPYRANOSIDURONATE-1,2-(METHYLORTHOACETATE) 95.00%
5MG
$ 503.16

Total 2 raw suppliers

Chemical Property of Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate)

Chemical Property:

PSA：115.82000
LogP:-0.51680
Storage Temp.:Refrigerator
Solubility.:Acetone, Chloroform, Dichloromethane, Ethanol, Ethyl Acetate, Methanol

Purity/Quality:

95% ^*data from raw suppliers

Methyl3,4-Di-O-acetyl-β-L-idopyranosiduronate1,2-(Methylorthoacetate) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Methyl 3,4-Di-O-acetyl-β-L-idopyranosiduronate 1,2-(Methylorthoacetate) (cas# 107952-66-9 ) is a compound useful in organic synthesis.

Technology Process of Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate)

There total 5 articles about Methyl 3,4-Di-O-acetyl--L-idopyranosiduronate, 1,2-(Methylorthoacetate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.4%

: 67-56-1
methanol

: 108032-44-6
methyl (2,3,4-tetra-O-acetyl-α-L-idopyranosyl bromide)uroate

: 107952-66-9
methyl 3,4-di-O-acetyl-β-L-idopyranouronate 1,2-(methyl orthoacetate)

Guidance literature:: With 2,4,6-trimethyl-pyridine; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1016/S0008-6215(00)90357-4

Reference yield:

: 108032-41-3
methyl 1,2,3,4-tetra-O-acetyl-α-L-idopyranuronate

: 107952-66-9
methyl 3,4-di-O-acetyl-β-L-idopyranouronate 1,2-(methyl orthoacetate)

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / 30percent HBr in AcOH / 4 h / Ambient temperature

2: 77.4 percent / 2,4,6-trimethylpyridine / CH₂Cl₂ / 24 h / Ambient temperature

With 2,4,6-trimethyl-pyridine; hydrogen bromide; In dichloromethane;
DOI:10.1016/S0008-6215(00)90357-4

Reference yield:

: 3082-96-0,5432-32-6,7355-18-2,19231-41-5,30628-06-9,30628-07-0,40268-90-4,40268-95-9,40269-24-7,104195-05-3,108032-41-3
methyl 1,2,3,4-tetra-O-acetyl-α,β-D-glucopyranosyluronate

: 107952-66-9,136598-87-3,136598-88-4
methyl 3,4-di-O-acetyl-1,2-O-(1-methoxyethylidene)-α-D-glucopyranuronate

Guidance literature:: Multi-step reaction with 2 steps

1: iodine / 1,2-dichloro-ethane / 0.5 h / Reflux

2: tetrabutylammomium bromide / methanol / 2 h / Reflux

With tetrabutylammomium bromide; iodine; In methanol; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201201084