Biphenyl-3,4′,5-tricarboxylic acid

Base Information

• Chemical Name: Biphenyl-3,4′,5-tricarboxylic acid
• CAS No.: 677010-20-7
• Molecular Formula: C15H10O6
• Molecular Weight: 286.241
• Hs Code.: 2917399090
• Mol file: 677010-20-7.mol

Synonyms:Biphenyl-3,4′,5-tricarboxylic acid;Biphenyl-3,4',5-tricarboxylic acid 96%;5-(4-carboxyphenyl)benzene-1,3-dicarboxylicacid;[1,1'-biphenyl]-3,4',5-tricarboxylic acid

Chemical Property of Biphenyl-3,4′,5-tricarboxylic acid

Chemical Property:

• Melting Point: >300°C
• Boiling Point: 627.7±55.0 °C(Predicted)
• PKA: 3.36±0.10(Predicted)
• PSA: 111.90000
• Density: 1.488±0.06 g/cm3(Predicted)
• LogP: 2.44820

Purity/Quality:

98%,99%, ^*data from raw suppliers

[1,1'-Biphenyl]-3,4',5-tricarboxylic Acid ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,N
• Statements: 36/37/38-50
• Safety Statements: 26-61

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Biphenyl-3,4′,5-tricarboxylic acid

There total 12 articles about Biphenyl-3,4′,5-tricarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

trimethyl 1,1'-biphenyl-3,4',5-tricarboxylate → biphenyl-3,4',5-tricarboxylic acid (677010-20-7)

Guidance literature:

With methanol; sodium hydroxide; In tetrahydrofuran;

Reference yield: 85.9%

1-(4-methylphenyl)-3,5-dimethylbenzene (7383-87-1) → biphenyl-3,4',5-tricarboxylic acid (677010-20-7)

Guidance literature:

With potassium permanganate; In pyridine; water; for 72h; Reflux;

DOI:10.1039/c0cc03482g

Reference yield:

methyl 4-carboxyphenylboronic acid + dimethyl 5-bromoisophthalate (51760-21-5) → biphenyl-3,4',5-tricarboxylic acid (677010-20-7)

Guidance literature:

With aqueous KOH; potassium carbonate; Pd(PPh₃)4; In 1,4-dioxane; ethanol; water; toluene;

upstream raw materials:

dimethyl 5-bromoisophthalate

1-(4-methylphenyl)-3,5-dimethylbenzene

4-methylphenylboronic acid

dimethyl 5-(pinacolboryl)isophthalate

Downstream raw materials:

{[Zn(HBPT)(1,3-bis(imidazol-1-ylmethyl)benzene)]*H₂O}_n

Refernces

• 1、 -. "Monocrystalline iron metal organic frameworks". Paragraph 0160; 0162. . Retrieved 2015/06/03.
• 2、 -. "Strategies, linkers and coordination polymers for high-performance sorbents". Page/Page column 21; 22. . Retrieved 2016/03/12.