51760-21-5

Basic information

• Product Name: DIMETHYL 5-BROMOISOPHTHALATE
• Synonyms: DiMethyl 5-broMoisophthalateALATE;Dimethyl 5-bromoisophthalate >=98.0% (GC);5-BROMOISOPHTHALIC ACID DIMETHYL ESTER;DIMETHYL 5-BROMOBENZENE-1,3-DICARBOXYLATE;DIMETHYL 5-BROMOISOPHTHALATE;3-benzenedicarboxylicacid,5-bromo-dimethylester;DIMETHYL 5-BROMOISOPHTHALAT;5-Bromo-1,3-benzenedicarboxylic acid dimethyl ester
• CAS NO: 51760-21-5
• Molecular Formula: C₁₀H₉BrO₄
• Molecular Weight: 273.08
• EINECS: 257-386-0
• Mol File: 51760-21-5.mol
• Article Data: 25

Chemical Properties

• Melting Point: 85-89 °C
• Boiling Point: 150 °C
• Flash Point: 100 °C
• Appearance: /
• Density: 1.505g/cm³
• Vapor Pressure: 0.000347mmHg at 25°C
• Refractive Index: 1.546
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility: Insoluble in water.
• BRN: 2375428
• CAS DataBase Reference: DIMETHYL 5-BROMOISOPHTHALATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMETHYL 5-BROMOISOPHTHALATE(51760-21-5)
• EPA Substance Registry System: DIMETHYL 5-BROMOISOPHTHALATE(51760-21-5)

Safety Data

• Hazard Codes: T,Xi
• Statements: 25
• Safety Statements: 45
• RIDADR: UN 2811 6.1/PG 3
• WGK Germany: 3
• TSCA: Yes
• HazardClass: IRRITANT
• PackingGroup: Ⅲ
• Hazardous Substances Data: 51760-21-5(Hazardous Substances Data)

Usage

Chemical Properties

White to beige to light yellow solid

Uses

Dimethyl 5-bromoisophthalate is used as pharmaceutical intermediate.

InChI:InChI=1/C10H9BrO4/c1-14-9(12)6-3-7(10(13)15-2)5-8(11)4-6/h3-5H,1-2H3

Upstream product

• 1459-93-4 dimethyl Isophthalate 
• 121-91-5 isophthalic acid 
• 51839-15-7 5-iodo-isophthalic acid dimethyl ester 
• 67-56-1 methanol 
• 57863-69-1 5-bromobenzene-1,3-dicarboxylic acid chloride 
• 23351-91-9 5-bromoisophthalic acid 
• 74-88-4 methyl iodide 
• 99-27-4 dimethyl 5-aminoisophthalate 

Downstream Products

• 21991-00-4 1,3-dimethyl 5-phenylbenzene-1,3-dicarboxylate 
• 217655-36-2 dimethyl 5-(2-phenyl-1-ethynyl)isophthalate 
• 313648-72-5 dimethyl 5-(trimethylsilylethynyl)benzene-1,3-dicarboxylate 
• 120173-41-3 5-bromobenzene-1,3-dicarbaldehyde 
• 220096-20-8 1-Bromo-3,5-bis(dimethoxymethyl)benzene 
• 220096-40-2 1,2-bis[di(3',5'-diformylphenyl)phosphanyl]ethane 
• 220096-47-9 1,2-bis[di(3',5'-diformylphenyl)phosphanyl]benzene 
• 220096-27-5 1,2-bis[di[3',5'-bis(dimethoxymethyl)phenyl]phosphanyl]ethane 
• 220096-34-4 1,2-bis[di[3',5'-bis(dimethoxymethyl)phenyl]phosphanyl]benzene 
• 1221400-20-9 5-(2-oxo-oxazolidin-3-yl)-isophthalic acid dimethyl ester 
• 1221400-16-3 5-(5-methyl-1,1-dioxo-1λ6-[1,2,5]thiadiazolidin-2-yl)-isophthalic acid dimethyl ester 
• 210969-59-8 dimethyl 5-(diethoxyphosphoryl)isophthalate 
• 1421351-58-7 C₃₄H₂₆O₄ 
• 1421351-60-1 C₄₆H₄₂O₄ 

Relevant articles and documents

Novel microporous metal-organic framework exhibiting high acetylene and methane storage capacities

A new organic hexacarboxylic acid, 5,5′,5″-(9H-carbazole-3,6,9-triyl)triisophthalic acid (H6CTIA), was developed to construct its first microporous metal-organic framework (MOF), Cu6(CTIA)2 (ZJU-70). With open metal sites and suitable pore sizes, this MOF exhibits high acetylene and methane storage capacities at room temperature.

Preparation method of room-temperature phosphorescent benzoate compound

The invention relates to a room-temperature phosphorescent benzoate compound. The benzoate compound is prepared by an efficient one-step method, and the prepared benzoate compound has obvious phosphorescence at room temperature, thereby broadening the application range of the benzoate compound. The product can be widely applied to phosphorescent materials.

A New Microporous Metal-Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature

We have successfully designed and synthesized a new tetracarboxylic linker, which constructed its first three-dimensional microporous metal-organic framework (MOF), [Cu2(DDPD)(H2O)2]?Gx (ZJU-13, H4DDPD=5,5'-(2,6-dihydroxynaphthalene-1,5-diyl)diisophthalic acid, ZJU=Zhejiang University, G = guest molecules) via solvothermal reaction. Due to open Cu2+ sites and optimized pore size, the activated ZJU-13a displays high separation selectivity for C2H2/CH4 of 74 and C2H2/CO2 of 12.5 at low pressure by using Ideal Adsorbed Solution Theory (IAST) simulation at room temperature.