7383-87-1Relevant articles and documents
Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes
Gao, Pin,Chen, Liang-An,Brown, M. Kevin
supporting information, p. 10653 - 10657 (2018/09/10)
A three-component coupling of aryl bromides, arylboron reagents, and alkenylarenes is presented. The method tolerates a variety of substitution patterns on all of the components. In particular, 1,2-disubstituted alkenylarenes are suitable and undergo highly diastereoselective diarylation.
C-H arylation of unactivated arenes with aryl halides catalyzed by cobalt porphyrin
To, Ching Tat,Chan, Tek Long,Li, Bao Zhu,Hui, Ying Ying,Kwok, Tsz Yiu,Lam, Suet Yu,Chan, Kin Shing
supporting information; experimental part, p. 1023 - 1026 (2011/03/20)
A general procedure for cobalt-catalyzed direct C-H arylation of unactivated arenes has been discovered. This method employs aryl halides as the direct coupling partners with arenes without using any Grignard-type reagents. This catalysis opens a new methodology for the preparation of symmetrical as well as unsymmetrical biaryls in a user-friendly approach.