10-Ketomyristic acid methyl ester

Base Information

• Chemical Name: 10-Ketomyristic acid methyl ester
• CAS No.: 692-85-3
• Molecular Formula: C₁₅H₂₈O₃
• Molecular Weight: 256.386
• Hs Code.: 2918300090
• Mol file: 692-85-3.mol

Synonyms:10-Ketomyristic acid methyl ester;10-Oxomyristic acid methyl ester;10-Oxotetradecanoic acid methyl ester

Chemical Property of 10-Ketomyristic acid methyl ester

Chemical Property:

• PSA: 43.37000
• LogP: 4.03950

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-Ketomyristic acid methyl ester

There total 8 articles about 10-Ketomyristic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

methyl 10-chloro-10-oxodecanoate (14065-32-8) + di-n-butylzinc (1119-90-0) → methyl 10-oxomyristate (692-85-3)

Guidance literature:

In diethyl ether; benzene; for 2h; Heating;

Reference yield:

o-Phenylen-1-(4-benzoylbenzoat)-2-myristat (71778-78-4) + 2,2-dimethoxy-propane (77-76-9) → methyl 8-oxomyristate (43119-59-1) + methyl 7-oxomyristate (54527-03-6) + methyl 9-oxomyristate (54527-04-7) + methyl 10-oxomyristate (692-85-3) + methyl 12-oxotetradecanoate (74515-89-2) + methyl 11-oxotetradecanoate (85194-01-0)

Guidance literature:

In tetrachloromethane; Product distribution; Ambient temperature; Irradiation; multistep reaction in dependence on solvents: MeCN; MeCN/H₂O;

Reference yield:

trans-1,2-Cyclohexandiyl-1-(4-benzoylbenzoat)-2-tetradecanoat (71778-79-5) + 2,2-dimethoxy-propane (77-76-9) → methyl 8-oxomyristate (43119-59-1) + methyl 7-oxomyristate (54527-03-6) + methyl 9-oxomyristate (54527-04-7) + methyl 10-oxomyristate (692-85-3) + methyl 12-oxotetradecanoate (74515-89-2) + methyl 11-oxotetradecanoate (85194-01-0)

Guidance literature:

In tetrachloromethane; Product distribution; Ambient temperature; Irradiation; multistep reaction in dependence on solvents: MeCN; MeCN/H₂O;

upstream raw materials:

1-bromo-butane

methyl 10-chloro-10-oxodecanoate

di-n-butylzinc

o-Phenylen-1-(4-benzoylbenzoat)-2-myristat

Downstream raw materials:

10-oxotetradecanoic acid