2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

Base Information

Chemical Name:2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde
CAS No.:1344738-10-8
Molecular Formula:C₁₅H₂₄O₂SSi
Molecular Weight:0
Hs Code.:
Mol file:1344738-10-8.mol

Synonyms:2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

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Chemical Property of 2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

Chemical Property:

Purity/Quality:

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Technology Process of 2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

There total 3 articles about 2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 1344738-25-5
{2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]phenyl}methanol

: 1344738-10-8
2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

Guidance literature:: {2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]phenyl}methanol; With barium permanganate; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;

With manganese(IV) oxide; In dichloromethane; Reflux; Inert atmosphere;
DOI:10.1021/jm200677b

Reference yield:

: 1344738-24-4
methyl 2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzoate

: 1344738-10-8
2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

2.1: barium permanganate / dichloromethane / 24 h / 20 °C / Inert atmosphere

2.2: Reflux; Inert atmosphere

With lithium aluminium tetrahydride; barium permanganate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jm200677b

Reference yield:

: 4892-02-8
Methyl thiosalicylate

: 1344738-10-8
2-[(2-{[tert-butyl(dimethyl)silyl]oxy}ethyl)thio]benzaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / N,N-dimethyl-formamide / 1 h / Inert atmosphere

1.2: 20 °C / Inert atmosphere

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3.1: barium permanganate / dichloromethane / 24 h / 20 °C / Inert atmosphere

3.2: Reflux; Inert atmosphere

With lithium aluminium tetrahydride; barium permanganate; sodium hydride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm200677b