5H-Dibenz[b,f]azepine-10,11-dione

Base Information

• Chemical Name: 5H-Dibenz[b,f]azepine-10,11-dione
• CAS No.: 19579-83-0
• Molecular Formula: C14H9NO2
• Molecular Weight: 223.23
• Mol file: 19579-83-0.mol

Synonyms:5H-Dibenz[b,f]azepine-10,11-dione;Dibenzazepine-10,11-dione;Dibenzazepinodione;Oxcarbazepine IMpurity (5H-Dibenz[b,f]azepine-10,11-dione)

Chemical Property of 5H-Dibenz[b,f]azepine-10,11-dione

Chemical Property:

• PSA: 49.93000
• LogP: 2.04150
• Storage Temp.: Refrigerator
• Solubility.: DMSO (Slightly)

Purity/Quality:

99.0% Min ^*data from raw suppliers

Dibenzazepine-10,11-dione ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 5H-Dibenz[b,f]azepine-10,11-dione is used as a reagent in the preparation of bifunctional dipolar electroluminescent template for optoelect ronic applications. Dibenzazepine-10,11-dione is an impurity of Oxcarbazepine (O869250). Dibenzazepine-10,11-dione is used as a reagent in the preparation of bifunctional dipolar electroluminescent template for optoelectronic applications.

Technology Process of 5H-Dibenz[b,f]azepine-10,11-dione

There total 15 articles about 5H-Dibenz[b,f]azepine-10,11-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

11-hydroxy-5,11-dihydro-dibenzo[b,f]azepin-10-one (866181-35-3) → 5H-dibenzazepine-10(11H),11-dione (19579-83-0)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1039/d0ob02606a

Reference yield: 90.0%

oxcarbazepine (28721-07-5) → 5H-dibenzazepine-10(11H),11-dione (19579-83-0)

Guidance literature:

With selenium(IV) oxide; In 1,4-dioxane; for 7h; Reflux;

DOI:10.3998/ark.5550190.p008.813

Reference yield: 78.0%

diphenylamine-2,2′-dicarboxaldehyde (49579-63-7) → 5H-dibenzazepine-10(11H),11-dione (19579-83-0)

Guidance literature:

With 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/d0ob02606a

upstream raw materials:

potassium acetate

11-hydroxy-5,11-dihydro-dibenzo[b,f]azepin-10-one

10,11-dihydro-5H-dibenzo[b,f]azepine-10,11-diol

dibenzoazepine