CID 16211704

Base Information

Chemical Name:CID 16211704
CAS No.:67826-92-0
Molecular Formula:C26H54B2N2
Molecular Weight:416.34
Hs Code.:
European Community (EC) Number:625-603-1
DSSTox Substance ID:DTXSID40583463
Mol file:67826-92-0.mol

Synonyms:67826-92-0;MFCD00077801;Boron,tetrahydro[m-(N,N,N',N'-tetramethyl-1,2-ethanediamine-kN:kN')]bis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)di-, stereoisomer;SCHEMBL15953445;DTXSID40583463;PUBCHEM_16211704;I0796;D91200;(+)-N,N'-Bis(monoisopinocampheylborane)-N,N,N',N'-tetramethylethylenediamine

Suppliers and Price of CID 16211704

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AK Scientific
(-)-Isopinocampheylborane TMEDA Complex
5g
$ 205.00

American Custom Chemicals Corporation
(-)-ISOPINO CAMPHEYLBORANE TETRA METHYL ETHYLENEDIAMINE COMPLEX 95.00%
5G
$ 876.21

Sigma-Aldrich
(?)-Isopinocampheylborane TMEDA complex
5g
$ 148.00

TCI Chemical
(-)-Isopinocampheylborane TMEDA Complex >98.0%(N)
5g
$ 113.00

Total 11 raw suppliers

Chemical Property of CID 16211704

Chemical Property:

Melting Point:139-141 °C(lit.)
PSA：6.48000
LogP:4.32980
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:412.4160099
Heavy Atom Count:30
Complexity:216

Purity/Quality:

97% ^*data from raw suppliers

(-)-Isopinocampheylborane TMEDA Complex ^*data from reagent suppliers

Safty Information:

Pictogram(s): F,Xi
Hazard Codes:F,Xi
Statements: 15-36/38
Safety Statements: 26-36-43

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[B]C1CC2CC(C1C)C2(C)C.[B]C1CC2CC(C1C)C2(C)C.CN(C)CCN(C)C
Isomeric SMILES:[B][C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.[B][C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.CN(C)CCN(C)C
Uses Chiral hydroboration reagent.This amine-borane complex has been used as a polarity-reversal catalyst for the kinetic resolution of racemic esters and ketones.

Technology Process of CID 16211704

There total 1 articles about CID 16211704 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 7785-26-4,25766-18-1
(-)-α-pinene

: 13292-87-0
dimethylsulfide borane complex

: 67826-92-0
(+)-alpine boramine TMEDA complex

Guidance literature:: (-)-α-pinene; dimethylsulfide borane complex; In diethyl ether; for 1h; Reflux;

N,N,N,N,-tetramethylethylenediamine; In diethyl ether; for 1h; Reflux;
DOI:10.1002/anie.201703340

Reference yield:

: 67826-92-0
(+)-alpine boramine TMEDA complex

: C₂₁H₃₁B

: 82248-44-0
((1S,2S)-2-Phenyl-cyclopentyl)-((1R,2S,3R,5R)-2,6,6-trimethyl-bicyclo[3.1.1]hept-3-yl)-borane

Guidance literature:: Multi-step reaction with 2 steps

1: boron trifluoride diethyl etherate / diethyl ether / 3 h / 20 °C

2: diethyl ether / 24 h / -78 - -25 °C

With boron trifluoride diethyl etherate; In diethyl ether;
DOI:10.1002/anie.201703340

Reference yield:

: 67826-92-0
(+)-alpine boramine TMEDA complex

: C₂₂H₃₃B

: C₂₂H₃₃B

Guidance literature:: Multi-step reaction with 2 steps

1: boron trifluoride diethyl etherate / diethyl ether / 3 h / 20 °C

2: diethyl ether / 48 h / -78 - -25 °C

With boron trifluoride diethyl etherate; In diethyl ether;
DOI:10.1002/anie.201703340