3-(Allyloxy)prop-1-EN-2-ylboronic acid pinacol ester

Base Information

Chemical Name:3-(Allyloxy)prop-1-EN-2-ylboronic acid pinacol ester
CAS No.:212127-71-4
Molecular Formula:C₁₂H₂₁BO₃
Molecular Weight:224.108
Hs Code.:
DSSTox Substance ID:DTXSID80453898
Nikkaji Number:J994.251C
Wikidata:Q82275183
Mol file:212127-71-4.mol

Synonyms:212127-71-4;3-(ALLYLOXY)PROP-1-EN-2-YLBORONIC ACID PINACOL ESTER;2-(3-(allyloxy)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-(3-prop-2-enoxyprop-1-en-2-yl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-[3-(prop-2-en-1-yloxy)prop-1-en-2-yl]-1,3,2-dioxaborolane;SCHEMBL2221968;DTXSID80453898;QNASSOWKHMKZMT-UHFFFAOYSA-N;AT16125;BS-28096;CS-0176206;FT-0731237;2-[1-[(Allyloxy)methyl]vinyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Suppliers and Price of 3-(Allyloxy)prop-1-EN-2-ylboronic acid pinacol ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
2-(3-(Allyloxy)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
1g
$ 395.00

Total 10 raw suppliers

Chemical Property of 3-(Allyloxy)prop-1-EN-2-ylboronic acid pinacol ester

Chemical Property:

Boiling Point:247.3±42.0 °C(Predicted)
PSA：27.69000
Density:0.93±0.1 g/cm3(Predicted)
LogP:2.37660
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:224.1583747
Heavy Atom Count:16
Complexity:268

Purity/Quality:

97% ^*data from raw suppliers

2-(3-(Allyloxy)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C(=C)COCC=C

Technology Process of 3-(Allyloxy)prop-1-EN-2-ylboronic acid pinacol ester

There total 2 articles about 3-(Allyloxy)prop-1-EN-2-ylboronic acid pinacol ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 61676-62-8
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 87279-92-3
2-bromo-2-propen-1-yl 2-propen-1-yl ether

: 212127-71-4
2-[3-(allyloxy)prop-1-en-2-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: 2-bromo-2-propen-1-yl 2-propen-1-yl ether; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 1h; Inert atmosphere;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In diethyl ether; pentane; at 0 - 20 ℃; for 1.4h; Inert atmosphere;
DOI:10.1002/ejoc.202000977

Reference yield:

: 51580-41-7
allyl propargyl ether

: 73183-34-3
bis(pinacol)diborane

: 212127-71-4
2-[3-(allyloxy)prop-1-en-2-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With copper(l) chloride; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate; In methanol; toluene; at 80 ℃; for 2h; regioselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.202000977