(SP-4-2-)-Dichloro[1,AS']platinum

Base Information

• Chemical Name: (SP-4-2-)-Dichloro[1,AS']platinum
• CAS No.: 14647-20-2
• Molecular Formula: C26H24 As2 Cl2 Pt
• Molecular Weight: 752.306
• NSC Number: 281280
• Mol file: 14647-20-2.mol

Synonyms:NSC281280;NSC-281280;(SP-4-2-)-DICHLORO[1,AS']PLATINUM;Platinum chloride-1,2-bis (diphenylarsine) ethane;Cl[Pt]1(Cl)[As](CC[As]1(c2ccccc2)c3ccccc3)(c4ccccc4)c5ccccc5;Platinum,2-ethanediylbis[diphenylarsine]-As,As']-, (SP-4-2)-;Platinum, dichloro[1,2-ethanediylbis[diphenylarsine]-As,As']-, (SP-4-2)-;14647-20-2

Chemical Property of (SP-4-2-)-Dichloro[1,AS']platinum

Chemical Property:

• Vapor Pressure: 1.88E-10mmHg at 25°C
• Boiling Point: 521.4°Cat760mmHg
• Flash Point: 270.7°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 752.94914
• Heavy Atom Count: 31
• Complexity: 367

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[AsH](CC[AsH](C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pt]Cl

Technology Process of (SP-4-2-)-Dichloro[1,AS']platinum

There total 8 articles about (SP-4-2-)-Dichloro[1,AS']platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,2-bis(diphenylarsino)ethane (4431-24-7) → dichloro{η2-1,2-bis(diphenylarsino)ethane}platinum(II) (14647-20-2)

Guidance literature:

In dichloromethane; room temp., N2 atm.; to a soln. of Pt-complex in CH2Cl2 solid diarsine was added, the mixt. was stirred at room temp. for 3 h; filtered, washed with diethyl ether, vac. dried; elem. anal.;

DOI:10.1039/b502196k

Reference yield:

{η2-1,2-bis(diphenylarsino)ethane}bis(4-methylphenyl)platinum(II) → dichloro{η2-1,2-bis(diphenylarsino)ethane}platinum(II) (14647-20-2) + (4,4'-dimethyl-1,1'-biphenyl) (613-33-2)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); irradiation of Pt complex soln., 16°C, 5h (Hg high pressure lamp, 313 and 330 nm); evapn.; chromy. (silica gel, CH2Cl2); identification by MS;

DOI:10.1016/0022-328X(89)87038-X

Reference yield:

{η2-1,2-bis(diphenylarsino)ethane}bis(4-fluorophenyl)platinum(II) → dichloro{η2-1,2-bis(diphenylarsino)ethane}platinum(II) (14647-20-2) + 4,4'-difluorobiphenyl (398-23-2)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); irradiation of Pt complex soln., 16°C, 5h (Hg high pressure lamp, 313 and 330 nm); evapn.; chromy. (silica gel, CH2Cl2); identification by MS;

DOI:10.1016/0022-328X(89)87038-X

upstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

1,2-bis(diphenylarsino)ethane

[Pt2(1,2-bis(diphenylarsino)ethane)2(μ-S)2]

dichloromethane

Downstream raw materials:

[Pt(3,5-dimethylpyrazolato)(1,2-bis(diphenylarsino)ethane)]

[Pt((C₆H₅)2AsCH₂CH₂As(C₆H₅)2)Cl₄]

[Pt2(1,2-bis(diphenylarsino)ethane)2(μ-S)2]