2-(Benzyloxy)-1,3-dichlorobenzene

Base Information

• Chemical Name: 2-(Benzyloxy)-1,3-dichlorobenzene
• CAS No.: 21524-44-7
• Molecular Formula: C13H10Cl2O
• Molecular Weight: 253.128
• Hs Code.: 2909309090
• Mol file: 21524-44-7.mol

Synonyms:2-(Benzyloxy)-1,3-dichlorobenzene

Chemical Property of 2-(Benzyloxy)-1,3-dichlorobenzene

Chemical Property:

• Melting Point: 39.5-40 °C
• Boiling Point: 194-195 °C(Press: 15 Torr)
• PSA: 9.23000
• Density: 1.278±0.06 g/cm3(Predicted)
• LogP: 4.57240
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

2-(Benzyloxy)-1,3-dichlorobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 2-(Benzyloxy)-1,3-dichlorobenzene is used in the synthesis of benzylic sulfonium salts.

Technology Process of 2-(Benzyloxy)-1,3-dichlorobenzene

There total 5 articles about 2-(Benzyloxy)-1,3-dichlorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2,6-Dichlorophenol (87-65-0) + toluene (108-88-3,15644-74-3,16713-13-6) → 2-benzyloxy-1,3-dichlorobenzene (21524-44-7)

Guidance literature:

With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium; at 130 ℃; for 24h; Green chemistry;

Reference yield:

2,6-Dichlorophenol (87-65-0) + benzyl alcohol (100-51-6,185532-71-2) → 2-benzyloxy-1,3-dichlorobenzene (21524-44-7) + 4-benzyl-2,6-dichloro-phenol (38932-58-0)

Guidance literature:

With aluminium trichloride; Petroleum ether;

DOI:10.1021/ja01357a031

Reference yield:

aluminium trichloride (7446-70-0) + 2,6-Dichlorophenol (87-65-0) + benzyl alcohol (100-51-6,185532-71-2) → 2-benzyloxy-1,3-dichlorobenzene (21524-44-7) + 4-benzyl-2,6-dichloro-phenol (38932-58-0)

Guidance literature:

DOI:10.1021/ja01357a031

upstream raw materials:

2,6-Dichlorophenol

benzyl alcohol

aluminium trichloride

benzyl chloride