1,3-Bis(ethylamino)benzene

Base Information

• Chemical Name: 1,3-Bis(ethylamino)benzene
• CAS No.: 5857-99-8
• Molecular Formula: C10H16N2
• Molecular Weight: 164.25
• Hs Code.: 2921519090
• Mol file: 5857-99-8.mol

Synonyms:1,3-Bis(ethylamino)benzene;N,N'-Diethyl-m-phenylenediamine;N1,N3-Diethylbenzene-1,3-diaMine

Chemical Property of 1,3-Bis(ethylamino)benzene

Chemical Property:

• PSA: 24.06000
• LogP: 2.69620
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

N1,N3-Diethylbenzene-1,3-diamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Bis(ethylamino)benzene

There total 2 articles about 1,3-Bis(ethylamino)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

ethanol (64-17-5) + m-phenylenediamine (108-45-2,64554-26-3,76583-20-5) → N,N’-diethyl-m-phenylenediamine (5857-99-8)

Guidance literature:

With cesiumhydroxide monohydrate; [(1,3-phenylene)bis(methylene)]bis(1-benzyl-4,5-dihydroimidazol-2-ylidene)bis[dicarbonyliridium(I) chloride]; at 120 ℃; for 48h; Molecular sieve; Green chemistry;

DOI:10.1055/s-0032-1317936

Reference yield:

→ N,N’-diethyl-m-phenylenediamine (5857-99-8)

Guidance literature:

entspr. N,N'-diacetylphenylenediamine, LiAlH4;

Reference yield: 80.0%

2-Iodobenzoyl chloride (609-67-6) + N,N’-diethyl-m-phenylenediamine (5857-99-8) → C24H22I2N2O2 (1263375-89-8)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 20 ℃; for 3h;

DOI:10.1080/00397910903531870

upstream raw materials:

ethanol

m-phenylenediamine

Downstream raw materials:

C₂₄H₂₂I₂N₂O₂

Refernces

• 1、 Kuo, Hsin-Ya,Liu, Yi-Hong,Peng, Shie-Ming,Liu, Shiuh-Tzung. "N,N′-dialkylation catalyzed by bimetallic iridium complexes containing a saturated bis-N-heterocyclic carbene (NHC) ligand". . p. 7248 - 7255,8. Retrieved 2020/09/02.